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μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)

In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl­ethylenedi­am...

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Detalles Bibliográficos
Autores principales: Corfield, Peter W. R., Michalski, Joseph F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998273/
https://www.ncbi.nlm.nih.gov/pubmed/24764834
http://dx.doi.org/10.1107/S160053681400172X
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author Corfield, Peter W. R.
Michalski, Joseph F.
author_facet Corfield, Peter W. R.
Michalski, Joseph F.
author_sort Corfield, Peter W. R.
collection PubMed
description In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl­ethylenedi­amine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group and to two terminal cyanide groups. In the crystal, N—H⋯N hydrogen bonds involving two of the symmetry-unique N—H groups of the N-ethyl­ethylenedi­amine ligands and the N atoms of the terminal cyanide ligands link the mol­ecules into strands along [010].
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spelling pubmed-39982732014-04-24 μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I) Corfield, Peter W. R. Michalski, Joseph F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl­ethylenedi­amine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group and to two terminal cyanide groups. In the crystal, N—H⋯N hydrogen bonds involving two of the symmetry-unique N—H groups of the N-ethyl­ethylenedi­amine ligands and the N atoms of the terminal cyanide ligands link the mol­ecules into strands along [010]. International Union of Crystallography 2014-01-31 /pmc/articles/PMC3998273/ /pubmed/24764834 http://dx.doi.org/10.1107/S160053681400172X Text en © Corfield and Michalski 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Corfield, Peter W. R.
Michalski, Joseph F.
μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title_full μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title_fullStr μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title_full_unstemmed μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title_short μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis­(N-ethyl­ethylenedi­amine-κ(2) N,N′)copper(II)copper(I)
title_sort μ-cyanido-κ(2) c:n-dicyanido-κ(2) c-bis­(n-ethyl­ethylenedi­amine-κ(2) n,n′)copper(ii)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998273/
https://www.ncbi.nlm.nih.gov/pubmed/24764834
http://dx.doi.org/10.1107/S160053681400172X
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