Cargando…
μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis(N-ethylethylenediamine-κ(2) N,N′)copper(II)copper(I)
In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethylethylenediam...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998273/ https://www.ncbi.nlm.nih.gov/pubmed/24764834 http://dx.doi.org/10.1107/S160053681400172X |
_version_ | 1782313325804126208 |
---|---|
author | Corfield, Peter W. R. Michalski, Joseph F. |
author_facet | Corfield, Peter W. R. Michalski, Joseph F. |
author_sort | Corfield, Peter W. R. |
collection | PubMed |
description | In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethylethylenediamine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group and to two terminal cyanide groups. In the crystal, N—H⋯N hydrogen bonds involving two of the symmetry-unique N—H groups of the N-ethylethylenediamine ligands and the N atoms of the terminal cyanide ligands link the molecules into strands along [010]. |
format | Online Article Text |
id | pubmed-3998273 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982732014-04-24 μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis(N-ethylethylenediamine-κ(2) N,N′)copper(II)copper(I) Corfield, Peter W. R. Michalski, Joseph F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(I)Cu(II)(CN)(3)(C(4)H(12)N(2))(2)], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethylethylenediamine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group and to two terminal cyanide groups. In the crystal, N—H⋯N hydrogen bonds involving two of the symmetry-unique N—H groups of the N-ethylethylenediamine ligands and the N atoms of the terminal cyanide ligands link the molecules into strands along [010]. International Union of Crystallography 2014-01-31 /pmc/articles/PMC3998273/ /pubmed/24764834 http://dx.doi.org/10.1107/S160053681400172X Text en © Corfield and Michalski 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Corfield, Peter W. R. Michalski, Joseph F. μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis(N-ethylethylenediamine-κ(2) N,N′)copper(II)copper(I) |
title | μ-Cyanido-κ(2)
C:N-dicyanido-κ(2)
C-bis(N-ethylethylenediamine-κ(2)
N,N′)copper(II)copper(I) |
title_full | μ-Cyanido-κ(2)
C:N-dicyanido-κ(2)
C-bis(N-ethylethylenediamine-κ(2)
N,N′)copper(II)copper(I) |
title_fullStr | μ-Cyanido-κ(2)
C:N-dicyanido-κ(2)
C-bis(N-ethylethylenediamine-κ(2)
N,N′)copper(II)copper(I) |
title_full_unstemmed | μ-Cyanido-κ(2)
C:N-dicyanido-κ(2)
C-bis(N-ethylethylenediamine-κ(2)
N,N′)copper(II)copper(I) |
title_short | μ-Cyanido-κ(2)
C:N-dicyanido-κ(2)
C-bis(N-ethylethylenediamine-κ(2)
N,N′)copper(II)copper(I) |
title_sort | μ-cyanido-κ(2)
c:n-dicyanido-κ(2)
c-bis(n-ethylethylenediamine-κ(2)
n,n′)copper(ii)copper(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998273/ https://www.ncbi.nlm.nih.gov/pubmed/24764834 http://dx.doi.org/10.1107/S160053681400172X |
work_keys_str_mv | AT corfieldpeterwr mcyanidok2cndicyanidok2cbisnethylethylenediaminek2nncopperiicopperi AT michalskijosephf mcyanidok2cndicyanidok2cbisnethylethylenediaminek2nncopperiicopperi |