1-Carb­oxy­naphthalen-2-yl acetate monohydrate

In the title compound, C(13)H(10)O(4)·H(2)O, both the carboxylic acid [C(ar)—C(ar)—C—O = −121.1 (2)°, where ar = aromatic] and the ester [C(ar)—C(ar)—O—C = −104.4 (3)°] groups lie out of the mean plane of the conjugated aromatic system. In the crystal, the organic mol­ecule is hydrogen bonded to wat...

Descripción completa

Detalles Bibliográficos
Autores principales: Souza, Bruno S., Bortoluzzi, Adailton J., Nome, Faruk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998276/
https://www.ncbi.nlm.nih.gov/pubmed/24764837
http://dx.doi.org/10.1107/S1600536813034338
Descripción
Sumario:In the title compound, C(13)H(10)O(4)·H(2)O, both the carboxylic acid [C(ar)—C(ar)—C—O = −121.1 (2)°, where ar = aromatic] and the ester [C(ar)—C(ar)—O—C = −104.4 (3)°] groups lie out of the mean plane of the conjugated aromatic system. In the crystal, the organic mol­ecule is hydrogen bonded to water mol­ecules through the ester and carb­oxy moieties, forming chains along the a-axis direction. The methyl H atoms of the acet­oxy group are disordered over two equally occupied sites.

Ejemplares similares