2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine

The title synthetic analog of purine nucleosides, C(16)H(16)Cl(2)N(4)O(7), has its acetyl­ated β-furan­ose ring in a 3′β-envelope conformation, with the corresponding C atom deviating by 0.602 (5) Å from the rest of the ring. The planar part of the furan­ose ring forms a dihedral angle of 65.0 (1)°...

Descripción completa

Detalles Bibliográficos
Autores principales: Novosjolova, Irina, Stepanovs, Dmitrijs, Bizdēna, Ērika, Mishnev, Anatoly, Turks, Māris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998279/
https://www.ncbi.nlm.nih.gov/pubmed/24764840
http://dx.doi.org/10.1107/S1600536813034521
_version_ 1782313327167275008
author Novosjolova, Irina
Stepanovs, Dmitrijs
Bizdēna, Ērika
Mishnev, Anatoly
Turks, Māris
author_facet Novosjolova, Irina
Stepanovs, Dmitrijs
Bizdēna, Ērika
Mishnev, Anatoly
Turks, Māris
author_sort Novosjolova, Irina
collection PubMed
description The title synthetic analog of purine nucleosides, C(16)H(16)Cl(2)N(4)O(7), has its acetyl­ated β-furan­ose ring in a 3′β-envelope conformation, with the corresponding C atom deviating by 0.602 (5) Å from the rest of the ring. The planar part of the furan­ose ring forms a dihedral angle of 65.0 (1)° with the mean plane of the purine bicycle. In the crystal, mol­ecules form a three-dimensional network through multiple C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interactions.
format Online
Article
Text
id pubmed-3998279
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39982792014-04-24 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine Novosjolova, Irina Stepanovs, Dmitrijs Bizdēna, Ērika Mishnev, Anatoly Turks, Māris Acta Crystallogr Sect E Struct Rep Online Organic Papers The title synthetic analog of purine nucleosides, C(16)H(16)Cl(2)N(4)O(7), has its acetyl­ated β-furan­ose ring in a 3′β-envelope conformation, with the corresponding C atom deviating by 0.602 (5) Å from the rest of the ring. The planar part of the furan­ose ring forms a dihedral angle of 65.0 (1)° with the mean plane of the purine bicycle. In the crystal, mol­ecules form a three-dimensional network through multiple C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interactions. International Union of Crystallography 2014-01-04 /pmc/articles/PMC3998279/ /pubmed/24764840 http://dx.doi.org/10.1107/S1600536813034521 Text en © Novosjolova et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Novosjolova, Irina
Stepanovs, Dmitrijs
Bizdēna, Ērika
Mishnev, Anatoly
Turks, Māris
2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title_full 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title_fullStr 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title_full_unstemmed 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title_short 2,6-Di­chloro-9-(2′,3′,5′-tri-O-acetyl-β-d-ribo­furanos­yl)-9H-purine
title_sort 2,6-di­chloro-9-(2′,3′,5′-tri-o-acetyl-β-d-ribo­furanos­yl)-9h-purine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998279/
https://www.ncbi.nlm.nih.gov/pubmed/24764840
http://dx.doi.org/10.1107/S1600536813034521
work_keys_str_mv AT novosjolovairina 26dichloro9235trioacetylbdribofuranosyl9hpurine
AT stepanovsdmitrijs 26dichloro9235trioacetylbdribofuranosyl9hpurine
AT bizdenaerika 26dichloro9235trioacetylbdribofuranosyl9hpurine
AT mishnevanatoly 26dichloro9235trioacetylbdribofuranosyl9hpurine
AT turksmaris 26dichloro9235trioacetylbdribofuranosyl9hpurine

Ejemplares similares