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(E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide
The molecule of the title compound, C(16)H(17)N(3)O(2)S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998281/ https://www.ncbi.nlm.nih.gov/pubmed/24764842 http://dx.doi.org/10.1107/S1600536813034892 |
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author | Sajitha, N. R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Sajitha, N. R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Sajitha, N. R. |
collection | PubMed |
description | The molecule of the title compound, C(16)H(17)N(3)O(2)S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a dihedral angle of 9.43 (9)° with the central benzene ring. The benzene rings are inclined to one another by 67.55 (12)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond involving the azomethine N atom. In the crystal, molecules are linked through weak N—H⋯S and N—H⋯O hydrogen bonds into double ribbons along [010]. The crystal packing also features C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3998281 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982812014-04-24 (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide Sajitha, N. R. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(16)H(17)N(3)O(2)S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a dihedral angle of 9.43 (9)° with the central benzene ring. The benzene rings are inclined to one another by 67.55 (12)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond involving the azomethine N atom. In the crystal, molecules are linked through weak N—H⋯S and N—H⋯O hydrogen bonds into double ribbons along [010]. The crystal packing also features C—H⋯π interactions. International Union of Crystallography 2014-01-08 /pmc/articles/PMC3998281/ /pubmed/24764842 http://dx.doi.org/10.1107/S1600536813034892 Text en © Sajitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sajitha, N. R. Sithambaresan, M. Kurup, M. R. Prathapachandra (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title_full | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title_fullStr | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title_full_unstemmed | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title_short | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
title_sort | (e)-2-(4-benzyloxy-2-hydroxybenzylidene)-n-methylhydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998281/ https://www.ncbi.nlm.nih.gov/pubmed/24764842 http://dx.doi.org/10.1107/S1600536813034892 |
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