2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline

The 21 non-H atoms of the title compound, C(15)H(10)Cl(2)N(4), are almost planar (r.m.s. deviation = 0.032 Å); the conformation about the N=C bond [1.277 (6) Å] is E. In the crystal, zigzag supra­molecular chains along the c axis (glide symmetry) are formed via N—H⋯N hydrogen bonds. These associate...

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Detalles Bibliográficos
Autores principales: Noguiera, Thais C. M., Pinheiro, Alexandra C., de Souza, Marcus V. N., Wardell, James L., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998292/
https://www.ncbi.nlm.nih.gov/pubmed/24764853
http://dx.doi.org/10.1107/S1600536814000415
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author Noguiera, Thais C. M.
Pinheiro, Alexandra C.
de Souza, Marcus V. N.
Wardell, James L.
Tiekink, Edward R. T.
author_facet Noguiera, Thais C. M.
Pinheiro, Alexandra C.
de Souza, Marcus V. N.
Wardell, James L.
Tiekink, Edward R. T.
author_sort Noguiera, Thais C. M.
collection PubMed
description The 21 non-H atoms of the title compound, C(15)H(10)Cl(2)N(4), are almost planar (r.m.s. deviation = 0.032 Å); the conformation about the N=C bond [1.277 (6) Å] is E. In the crystal, zigzag supra­molecular chains along the c axis (glide symmetry) are formed via N—H⋯N hydrogen bonds. These associate along the b axis by π–π inter­actions between the fused and terminal benzene rings [inter­centroid distance = 3.602 (3) Å] so that layers form in the bc plane.
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spelling pubmed-39982922014-04-24 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline Noguiera, Thais C. M. Pinheiro, Alexandra C. de Souza, Marcus V. N. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 21 non-H atoms of the title compound, C(15)H(10)Cl(2)N(4), are almost planar (r.m.s. deviation = 0.032 Å); the conformation about the N=C bond [1.277 (6) Å] is E. In the crystal, zigzag supra­molecular chains along the c axis (glide symmetry) are formed via N—H⋯N hydrogen bonds. These associate along the b axis by π–π inter­actions between the fused and terminal benzene rings [inter­centroid distance = 3.602 (3) Å] so that layers form in the bc plane. International Union of Crystallography 2014-01-11 /pmc/articles/PMC3998292/ /pubmed/24764853 http://dx.doi.org/10.1107/S1600536814000415 Text en © Noguiera et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Noguiera, Thais C. M.
Pinheiro, Alexandra C.
de Souza, Marcus V. N.
Wardell, James L.
Tiekink, Edward R. T.
2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title_full 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title_fullStr 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title_full_unstemmed 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title_short 2-[(E)-2-(3,4-Di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
title_sort 2-[(e)-2-(3,4-di­chloro­benzyl­idene)hydrazin-1-yl]quinoxaline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998292/
https://www.ncbi.nlm.nih.gov/pubmed/24764853
http://dx.doi.org/10.1107/S1600536814000415
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