Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate

The asymmetric unit of the title compound, C(18)H(16)N(6)Se·0.5CH(3)OH, contains two independent mol­ecules of bis­[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide with similar C—Se—C bond angles [99.30 (14) and 98.26 (13)°], and a methanol molecule of solvation. In one mol­ecule, the dihedral a...

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Autores principales: Seredyuk, Maksym, Sharkina, Natalia O., Gumienna-Kontecka, Elzbieta, Kapshuk, Anatoly A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998294/
https://www.ncbi.nlm.nih.gov/pubmed/24764855
http://dx.doi.org/10.1107/S1600536813034624
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author Seredyuk, Maksym
Sharkina, Natalia O.
Gumienna-Kontecka, Elzbieta
Kapshuk, Anatoly A.
author_facet Seredyuk, Maksym
Sharkina, Natalia O.
Gumienna-Kontecka, Elzbieta
Kapshuk, Anatoly A.
author_sort Seredyuk, Maksym
collection PubMed
description The asymmetric unit of the title compound, C(18)H(16)N(6)Se·0.5CH(3)OH, contains two independent mol­ecules of bis­[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide with similar C—Se—C bond angles [99.30 (14) and 98.26 (13)°], and a methanol molecule of solvation. In one mol­ecule, the dihedral angles between pyrazole and neighbouring pyridine rings are 18.3 (2) and 15.8 (2)°, and the corresponding angles in the other mol­ecule are 13.5 (2) and 8.3 (2)°. In the crystal, the selenide and solvent mol­ecules are linked by classical O—H⋯N and N—H⋯N hydrogen bonds, as well as by weak C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional supra­molecular architecture.
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spelling pubmed-39982942014-04-24 Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate Seredyuk, Maksym Sharkina, Natalia O. Gumienna-Kontecka, Elzbieta Kapshuk, Anatoly A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(16)N(6)Se·0.5CH(3)OH, contains two independent mol­ecules of bis­[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide with similar C—Se—C bond angles [99.30 (14) and 98.26 (13)°], and a methanol molecule of solvation. In one mol­ecule, the dihedral angles between pyrazole and neighbouring pyridine rings are 18.3 (2) and 15.8 (2)°, and the corresponding angles in the other mol­ecule are 13.5 (2) and 8.3 (2)°. In the crystal, the selenide and solvent mol­ecules are linked by classical O—H⋯N and N—H⋯N hydrogen bonds, as well as by weak C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional supra­molecular architecture. International Union of Crystallography 2014-01-11 /pmc/articles/PMC3998294/ /pubmed/24764855 http://dx.doi.org/10.1107/S1600536813034624 Text en © Seredyuk et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Seredyuk, Maksym
Sharkina, Natalia O.
Gumienna-Kontecka, Elzbieta
Kapshuk, Anatoly A.
Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title_full Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title_fullStr Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title_full_unstemmed Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title_short Bis[3-methyl-5-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide methanol hemisolvate
title_sort bis[3-methyl-5-(pyridin-2-yl)-1h-pyrazol-4-yl] selenide methanol hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998294/
https://www.ncbi.nlm.nih.gov/pubmed/24764855
http://dx.doi.org/10.1107/S1600536813034624
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AT gumiennakonteckaelzbieta bis3methyl5pyridin2yl1hpyrazol4ylselenidemethanolhemisolvate
AT kapshukanatolya bis3methyl5pyridin2yl1hpyrazol4ylselenidemethanolhemisolvate

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