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Diethylammonium dihydrogen orthophosphate
In the title molecular salt, [NH(2)(CH(2)CH(3))(2)][H(2)PO(4)], two unique types of cations and anions, which are configurationally very similar, are present in the asymmetric unit. Both ions form sheets approximately parallel to (-1-1) linked by weak hydrogen bonds. The interconnection within and...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998295/ https://www.ncbi.nlm.nih.gov/pubmed/24764856 http://dx.doi.org/10.1107/S1600536814000464 |
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author | Held, Peter |
author_facet | Held, Peter |
author_sort | Held, Peter |
collection | PubMed |
description | In the title molecular salt, [NH(2)(CH(2)CH(3))(2)][H(2)PO(4)], two unique types of cations and anions, which are configurationally very similar, are present in the asymmetric unit. Both ions form sheets approximately parallel to (-1-1) linked by weak hydrogen bonds. The interconnection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds involving the tetrahedral H(2)PO(4) anions and the ammonium groups. |
format | Online Article Text |
id | pubmed-3998295 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982952014-04-24 Diethylammonium dihydrogen orthophosphate Held, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, [NH(2)(CH(2)CH(3))(2)][H(2)PO(4)], two unique types of cations and anions, which are configurationally very similar, are present in the asymmetric unit. Both ions form sheets approximately parallel to (-1-1) linked by weak hydrogen bonds. The interconnection within and between the sheets is reinforced by O—H⋯O and N—H⋯O hydrogen bonds involving the tetrahedral H(2)PO(4) anions and the ammonium groups. International Union of Crystallography 2014-01-11 /pmc/articles/PMC3998295/ /pubmed/24764856 http://dx.doi.org/10.1107/S1600536814000464 Text en © Peter Held 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Held, Peter Diethylammonium dihydrogen orthophosphate |
title | Diethylammonium dihydrogen orthophosphate |
title_full | Diethylammonium dihydrogen orthophosphate |
title_fullStr | Diethylammonium dihydrogen orthophosphate |
title_full_unstemmed | Diethylammonium dihydrogen orthophosphate |
title_short | Diethylammonium dihydrogen orthophosphate |
title_sort | diethylammonium dihydrogen orthophosphate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998295/ https://www.ncbi.nlm.nih.gov/pubmed/24764856 http://dx.doi.org/10.1107/S1600536814000464 |
work_keys_str_mv | AT heldpeter diethylammoniumdihydrogenorthophosphate |