1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one

The title compound, C(12)H(14)N(2)O(3)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both mol­ecules are twisted about the C—C bond. In the crystal, the A and B mol­ecules are associated via pairs of N—H⋯O hydrogen bond...

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Detalles Bibliográficos
Autores principales: Mague, Joel T., Abdel-Aziz, Alaa A.-M., El-Azab, Adel S., Alanazi, Amer M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998308/
https://www.ncbi.nlm.nih.gov/pubmed/24764869
http://dx.doi.org/10.1107/S1600536814000117
Descripción
Sumario:The title compound, C(12)H(14)N(2)O(3)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both mol­ecules are twisted about the C—C bond. In the crystal, the A and B mol­ecules are associated via pairs of N—H⋯O hydrogen bonds, forming A–B dimers. These dimers are linked via C—H⋯S hydrogen bonds, forming double dimers, which are in turn linked via C—H⋯O hydrogen bonds forming two-dimensional networks lying parallel to (001). There are also C—H⋯π inter­actions present, which consolide the layers and link them, so forming a three-dimensional structure.

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