1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one

The title compound, C(12)H(14)N(2)O(3)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both mol­ecules are twisted about the C—C bond. In the crystal, the A and B mol­ecules are associated via pairs of N—H⋯O hydrogen bond...

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Autores principales: Mague, Joel T., Abdel-Aziz, Alaa A.-M., El-Azab, Adel S., Alanazi, Amer M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998308/
https://www.ncbi.nlm.nih.gov/pubmed/24764869
http://dx.doi.org/10.1107/S1600536814000117
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author Mague, Joel T.
Abdel-Aziz, Alaa A.-M.
El-Azab, Adel S.
Alanazi, Amer M.
author_facet Mague, Joel T.
Abdel-Aziz, Alaa A.-M.
El-Azab, Adel S.
Alanazi, Amer M.
author_sort Mague, Joel T.
collection PubMed
description The title compound, C(12)H(14)N(2)O(3)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both mol­ecules are twisted about the C—C bond. In the crystal, the A and B mol­ecules are associated via pairs of N—H⋯O hydrogen bonds, forming A–B dimers. These dimers are linked via C—H⋯S hydrogen bonds, forming double dimers, which are in turn linked via C—H⋯O hydrogen bonds forming two-dimensional networks lying parallel to (001). There are also C—H⋯π inter­actions present, which consolide the layers and link them, so forming a three-dimensional structure.
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spelling pubmed-39983082014-04-24 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one Mague, Joel T. Abdel-Aziz, Alaa A.-M. El-Azab, Adel S. Alanazi, Amer M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(14)N(2)O(3)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The five-membered imidazolidin-2-one rings in both mol­ecules are twisted about the C—C bond. In the crystal, the A and B mol­ecules are associated via pairs of N—H⋯O hydrogen bonds, forming A–B dimers. These dimers are linked via C—H⋯S hydrogen bonds, forming double dimers, which are in turn linked via C—H⋯O hydrogen bonds forming two-dimensional networks lying parallel to (001). There are also C—H⋯π inter­actions present, which consolide the layers and link them, so forming a three-dimensional structure. International Union of Crystallography 2014-01-15 /pmc/articles/PMC3998308/ /pubmed/24764869 http://dx.doi.org/10.1107/S1600536814000117 Text en © Mague et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mague, Joel T.
Abdel-Aziz, Alaa A.-M.
El-Azab, Adel S.
Alanazi, Amer M.
1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title_full 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title_fullStr 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title_full_unstemmed 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title_short 1-Acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
title_sort 1-acetyl-5-meth­oxy-4-(phenyl­sulfan­yl)imidazolidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998308/
https://www.ncbi.nlm.nih.gov/pubmed/24764869
http://dx.doi.org/10.1107/S1600536814000117
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AT alanaziamerm 1acetyl5methoxy4phenylsulfanylimidazolidin2one

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