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(E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate
The title compound crystallizes as a hemihydrate, C(18)H(20)N(2)O(5)·0.5H(2)O. The molecule exists in an E conformation with respect to the C=N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles betwee...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998312/ https://www.ncbi.nlm.nih.gov/pubmed/24764873 http://dx.doi.org/10.1107/S1600536814000531 |
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author | Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | The title compound crystallizes as a hemihydrate, C(18)H(20)N(2)O(5)·0.5H(2)O. The molecule exists in an E conformation with respect to the C=N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles between the benzene rings are 29.20 (9) and 26.59 (9)°, respectively, for the major and minor components of the 4-methoxy-substituted ring. All methoxy substituents lie close to the plane of the attached benzene rings [the C(methyl)—O—C—C torsion angles range from −4.0 (12) to 3.9 (2)°]. In the crystal, the components are linked into chains propagating along [001] via N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3998312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39983122014-04-24 (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound crystallizes as a hemihydrate, C(18)H(20)N(2)O(5)·0.5H(2)O. The molecule exists in an E conformation with respect to the C=N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0.46 (2). The dihedral angles between the benzene rings are 29.20 (9) and 26.59 (9)°, respectively, for the major and minor components of the 4-methoxy-substituted ring. All methoxy substituents lie close to the plane of the attached benzene rings [the C(methyl)—O—C—C torsion angles range from −4.0 (12) to 3.9 (2)°]. In the crystal, the components are linked into chains propagating along [001] via N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯O interactions. International Union of Crystallography 2014-01-15 /pmc/articles/PMC3998312/ /pubmed/24764873 http://dx.doi.org/10.1107/S1600536814000531 Text en © Chantrapromma et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Boonnak, Nawong Horkaew, Jirapa Quah, Ching Kheng Fun, Hoong-Kun (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title | (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title_full | (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title_fullStr | (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title_full_unstemmed | (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title_short | (E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
title_sort | (e)-4-methoxy-n′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998312/ https://www.ncbi.nlm.nih.gov/pubmed/24764873 http://dx.doi.org/10.1107/S1600536814000531 |
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