rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine

In the title compound, C(23)H(31)NO(2)S, the geometry of the triiso­propyl­phenyl group is slightly distorted, with elongated C—C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison,...

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Detalles Bibliográficos
Autores principales: Golz, Christopher, Preut, Hans, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998314/
https://www.ncbi.nlm.nih.gov/pubmed/24764875
http://dx.doi.org/10.1107/S1600536814000257
Descripción
Sumario:In the title compound, C(23)H(31)NO(2)S, the geometry of the triiso­propyl­phenyl group is slightly distorted, with elongated C—C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluene­sulfonyl­aziridine [Zhu et al. (2006 ▶). Acta Cryst. E62, o1507–o1508]. π–π inter­actions between adjacent benzene rings [centroid–centroid distance = 3.7928 (11) Å] and are observed.

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