rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine

In the title compound, C(23)H(31)NO(2)S, the geometry of the triiso­propyl­phenyl group is slightly distorted, with elongated C—C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison,...

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Detalles Bibliográficos
Autores principales: Golz, Christopher, Preut, Hans, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998314/
https://www.ncbi.nlm.nih.gov/pubmed/24764875
http://dx.doi.org/10.1107/S1600536814000257
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author Golz, Christopher
Preut, Hans
Strohmann, Carsten
author_facet Golz, Christopher
Preut, Hans
Strohmann, Carsten
author_sort Golz, Christopher
collection PubMed
description In the title compound, C(23)H(31)NO(2)S, the geometry of the triiso­propyl­phenyl group is slightly distorted, with elongated C—C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluene­sulfonyl­aziridine [Zhu et al. (2006 ▶). Acta Cryst. E62, o1507–o1508]. π–π inter­actions between adjacent benzene rings [centroid–centroid distance = 3.7928 (11) Å] and are observed.
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spelling pubmed-39983142014-04-24 rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine Golz, Christopher Preut, Hans Strohmann, Carsten Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(31)NO(2)S, the geometry of the triiso­propyl­phenyl group is slightly distorted, with elongated C—C bonds at the ipso-C atom, and an S atom which deviates from the benzene ring plane by 0.228 (2) Å. This distortion is caused by the bulky substituents and, in comparison, an unbent geometry is observed in N-toluene­sulfonyl­aziridine [Zhu et al. (2006 ▶). Acta Cryst. E62, o1507–o1508]. π–π inter­actions between adjacent benzene rings [centroid–centroid distance = 3.7928 (11) Å] and are observed. International Union of Crystallography 2014-01-15 /pmc/articles/PMC3998314/ /pubmed/24764875 http://dx.doi.org/10.1107/S1600536814000257 Text en © Golz et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Golz, Christopher
Preut, Hans
Strohmann, Carsten
rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title_full rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title_fullStr rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title_full_unstemmed rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title_short rac-2-Phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
title_sort rac-2-phenyl-1-[(2,4,6-triiso­propyl­benzene)­sulfon­yl]aziridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998314/
https://www.ncbi.nlm.nih.gov/pubmed/24764875
http://dx.doi.org/10.1107/S1600536814000257
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AT preuthans rac2phenyl1246triisopropylbenzenesulfonylaziridine
AT strohmanncarsten rac2phenyl1246triisopropylbenzenesulfonylaziridine

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