1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)

In the title salt C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), two 3-chloro­benzoate (3CBA) anions are bridged by one diprotonated 1,4-di­aza­bicyclo­[2.2.2]octane-1,4-diium (H(2)DABCO(2+)) dication through N—H⋯O hydrogen bonds. In this way, a trimeric unit is generated, in which the mean planes of the t...

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Detalles Bibliográficos
Autores principales: Yao, Zi-Shuo, Sato, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998315/
https://www.ncbi.nlm.nih.gov/pubmed/24764876
http://dx.doi.org/10.1107/S1600536814000610
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author Yao, Zi-Shuo
Sato, Osamu
author_facet Yao, Zi-Shuo
Sato, Osamu
author_sort Yao, Zi-Shuo
collection PubMed
description In the title salt C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), two 3-chloro­benzoate (3CBA) anions are bridged by one diprotonated 1,4-di­aza­bicyclo­[2.2.2]octane-1,4-diium (H(2)DABCO(2+)) dication through N—H⋯O hydrogen bonds. In this way, a trimeric unit is generated, in which the mean planes of the two 3CBA anions are twisted with respect to each other by a dihedral angle of 59.87 (9)°. The trimeric units are linked into a three-dimensional network via weak C—H⋯O inter­actions.
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spelling pubmed-39983152014-04-24 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate) Yao, Zi-Shuo Sato, Osamu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (−), two 3-chloro­benzoate (3CBA) anions are bridged by one diprotonated 1,4-di­aza­bicyclo­[2.2.2]octane-1,4-diium (H(2)DABCO(2+)) dication through N—H⋯O hydrogen bonds. In this way, a trimeric unit is generated, in which the mean planes of the two 3CBA anions are twisted with respect to each other by a dihedral angle of 59.87 (9)°. The trimeric units are linked into a three-dimensional network via weak C—H⋯O inter­actions. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998315/ /pubmed/24764876 http://dx.doi.org/10.1107/S1600536814000610 Text en © Yao and Sato 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yao, Zi-Shuo
Sato, Osamu
1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title_full 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title_fullStr 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title_full_unstemmed 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title_short 1,4-Di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
title_sort 1,4-di­aza­bicyclo­[2.2.2]octane-1,4-diium bis­(3-chloro­benzoate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998315/
https://www.ncbi.nlm.nih.gov/pubmed/24764876
http://dx.doi.org/10.1107/S1600536814000610
work_keys_str_mv AT yaozishuo 14diazabicyclo222octane14diiumbis3chlorobenzoate
AT satoosamu 14diazabicyclo222octane14diiumbis3chlorobenzoate

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