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1-Ethyl-3-methyl-1H-imidazol-3-ium spiro­penta­borate

In the anion of the title compound, (C(6)H(11)N(2))[B(5)O(6)(OH)(4)], both six-membered borate rings adopt a flattened boat conformation with the spiro-B atom and its opposite O atom deviating from the remainders of the rings by 0.261 (3)/0.101 (2) and 0.160 (3)/0.109 (2) Å, respectively. The imidaz...

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Detalles Bibliográficos
Autores principales: Parker, T. Gannon, Pubbi, Divya, Beehler, Austin, Albrecht-Schmitt, Thomas E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998326/
https://www.ncbi.nlm.nih.gov/pubmed/24764887
http://dx.doi.org/10.1107/S1600536813034363
Descripción
Sumario:In the anion of the title compound, (C(6)H(11)N(2))[B(5)O(6)(OH)(4)], both six-membered borate rings adopt a flattened boat conformation with the spiro-B atom and its opposite O atom deviating from the remainders of the rings by 0.261 (3)/0.101 (2) and 0.160 (3)/0.109 (2) Å, respectively. The imidazolium cation also deviates from planarity due to rotation of the ethyl group (as indicated by the C—N—C—C torsion angle) by 71.4 (2)° out of the plane of the heterocycle. In the crystal, the anions are connected in a three-dimensional network through O—H⋯O hydrogen bonds, forming channels along the a-axis direction. The cations are situated in the channels, forming C—H⋯O hydrogen bonds with the anions.