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1-Ethyl-3-methyl-1H-imidazol-3-ium spiropentaborate
In the anion of the title compound, (C(6)H(11)N(2))[B(5)O(6)(OH)(4)], both six-membered borate rings adopt a flattened boat conformation with the spiro-B atom and its opposite O atom deviating from the remainders of the rings by 0.261 (3)/0.101 (2) and 0.160 (3)/0.109 (2) Å, respectively. The imidaz...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998326/ https://www.ncbi.nlm.nih.gov/pubmed/24764887 http://dx.doi.org/10.1107/S1600536813034363 |
Sumario: | In the anion of the title compound, (C(6)H(11)N(2))[B(5)O(6)(OH)(4)], both six-membered borate rings adopt a flattened boat conformation with the spiro-B atom and its opposite O atom deviating from the remainders of the rings by 0.261 (3)/0.101 (2) and 0.160 (3)/0.109 (2) Å, respectively. The imidazolium cation also deviates from planarity due to rotation of the ethyl group (as indicated by the C—N—C—C torsion angle) by 71.4 (2)° out of the plane of the heterocycle. In the crystal, the anions are connected in a three-dimensional network through O—H⋯O hydrogen bonds, forming channels along the a-axis direction. The cations are situated in the channels, forming C—H⋯O hydrogen bonds with the anions. |
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