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Butane-1,4-di­ammonium hexa­fluoro­silicate

The title compound, [NH(3)(CH(2))(4)NH(3)](2+)·SiF(6) (2−), is a hybrid built from an organic butane-1,4-di­ammonium dication linked to a hexa­fluoro­silicate mineral anion. Both ions posses inversion symmetry. In the anion the Si atom is located on an inversion center, while in the cation the cente...

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Detalles Bibliográficos
Autores principales: Ouasri, Ali, Rhandour, Ali, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998328/
https://www.ncbi.nlm.nih.gov/pubmed/24764889
http://dx.doi.org/10.1107/S1600536814001068
Descripción
Sumario:The title compound, [NH(3)(CH(2))(4)NH(3)](2+)·SiF(6) (2−), is a hybrid built from an organic butane-1,4-di­ammonium dication linked to a hexa­fluoro­silicate mineral anion. Both ions posses inversion symmetry. In the anion the Si atom is located on an inversion center, while in the cation the center of inversion is situated at the mid-point of the central —CH(2)—CH(2)— bond. The Si atom is surrounded by six F atoms, forming a slightly distorted SiF(6) (2−) octa­hedron. These octa­hedra are linked to the organic cations through N—H⋯F hydrogen bonds, forming a three-dimensional network.