Butane-1,4-di­ammonium hexa­fluoro­silicate

The title compound, [NH(3)(CH(2))(4)NH(3)](2+)·SiF(6) (2−), is a hybrid built from an organic butane-1,4-di­ammonium dication linked to a hexa­fluoro­silicate mineral anion. Both ions posses inversion symmetry. In the anion the Si atom is located on an inversion center, while in the cation the cente...

Descripción completa

Detalles Bibliográficos
Autores principales: Ouasri, Ali, Rhandour, Ali, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998328/
https://www.ncbi.nlm.nih.gov/pubmed/24764889
http://dx.doi.org/10.1107/S1600536814001068
_version_ 1782313338362920960
author Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouasri, Ali
collection PubMed
description The title compound, [NH(3)(CH(2))(4)NH(3)](2+)·SiF(6) (2−), is a hybrid built from an organic butane-1,4-di­ammonium dication linked to a hexa­fluoro­silicate mineral anion. Both ions posses inversion symmetry. In the anion the Si atom is located on an inversion center, while in the cation the center of inversion is situated at the mid-point of the central —CH(2)—CH(2)— bond. The Si atom is surrounded by six F atoms, forming a slightly distorted SiF(6) (2−) octa­hedron. These octa­hedra are linked to the organic cations through N—H⋯F hydrogen bonds, forming a three-dimensional network.
format Online
Article
Text
id pubmed-3998328
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39983282014-04-24 Butane-1,4-di­ammonium hexa­fluoro­silicate Ouasri, Ali Rhandour, Ali Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, [NH(3)(CH(2))(4)NH(3)](2+)·SiF(6) (2−), is a hybrid built from an organic butane-1,4-di­ammonium dication linked to a hexa­fluoro­silicate mineral anion. Both ions posses inversion symmetry. In the anion the Si atom is located on an inversion center, while in the cation the center of inversion is situated at the mid-point of the central —CH(2)—CH(2)— bond. The Si atom is surrounded by six F atoms, forming a slightly distorted SiF(6) (2−) octa­hedron. These octa­hedra are linked to the organic cations through N—H⋯F hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998328/ /pubmed/24764889 http://dx.doi.org/10.1107/S1600536814001068 Text en © Ouasri et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ouasri, Ali
Rhandour, Ali
Saadi, Mohamed
El Ammari, Lahcen
Butane-1,4-di­ammonium hexa­fluoro­silicate
title Butane-1,4-di­ammonium hexa­fluoro­silicate
title_full Butane-1,4-di­ammonium hexa­fluoro­silicate
title_fullStr Butane-1,4-di­ammonium hexa­fluoro­silicate
title_full_unstemmed Butane-1,4-di­ammonium hexa­fluoro­silicate
title_short Butane-1,4-di­ammonium hexa­fluoro­silicate
title_sort butane-1,4-di­ammonium hexa­fluoro­silicate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998328/
https://www.ncbi.nlm.nih.gov/pubmed/24764889
http://dx.doi.org/10.1107/S1600536814001068
work_keys_str_mv AT ouasriali butane14diammoniumhexafluorosilicate
AT rhandourali butane14diammoniumhexafluorosilicate
AT saadimohamed butane14diammoniumhexafluorosilicate
AT elammarilahcen butane14diammoniumhexafluorosilicate

Ejemplares similares