5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione

In the title pymiridine-2,4-dione derivative, C(14)H(16)N(2)O(2)S, the dihedral angle between the six-membered rings is 66.69 (10)°. The mol­ecule is twisted about the C(p)—S (p = pyrimidine) bond, with a C—S—C—N torsion angle of −19.57 (16)°. In the crystal, adjacent mol­ecules form inversion dimer...

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Detalles Bibliográficos
Autores principales: Al-Omary, Fatmah A. M., Ghabbour, Hazem A., El-Emam, Ali A., Chidan Kumar, C. S., Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998333/
https://www.ncbi.nlm.nih.gov/pubmed/24764894
http://dx.doi.org/10.1107/S1600536814000749
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author Al-Omary, Fatmah A. M.
Ghabbour, Hazem A.
El-Emam, Ali A.
Chidan Kumar, C. S.
Fun, Hoong-Kun
author_facet Al-Omary, Fatmah A. M.
Ghabbour, Hazem A.
El-Emam, Ali A.
Chidan Kumar, C. S.
Fun, Hoong-Kun
author_sort Al-Omary, Fatmah A. M.
collection PubMed
description In the title pymiridine-2,4-dione derivative, C(14)H(16)N(2)O(2)S, the dihedral angle between the six-membered rings is 66.69 (10)°. The mol­ecule is twisted about the C(p)—S (p = pyrimidine) bond, with a C—S—C—N torsion angle of −19.57 (16)°. In the crystal, adjacent mol­ecules form inversion dimers through pairs of strong N—H⋯O hydrogen bonds, generating an R (2) (2)(8) ring motif. The dimers are connected into chains extending along the c-axis direction through additional N—H⋯O hydrogen bonds.
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spelling pubmed-39983332014-04-24 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione Al-Omary, Fatmah A. M. Ghabbour, Hazem A. El-Emam, Ali A. Chidan Kumar, C. S. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title pymiridine-2,4-dione derivative, C(14)H(16)N(2)O(2)S, the dihedral angle between the six-membered rings is 66.69 (10)°. The mol­ecule is twisted about the C(p)—S (p = pyrimidine) bond, with a C—S—C—N torsion angle of −19.57 (16)°. In the crystal, adjacent mol­ecules form inversion dimers through pairs of strong N—H⋯O hydrogen bonds, generating an R (2) (2)(8) ring motif. The dimers are connected into chains extending along the c-axis direction through additional N—H⋯O hydrogen bonds. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998333/ /pubmed/24764894 http://dx.doi.org/10.1107/S1600536814000749 Text en © Al-Omary et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Omary, Fatmah A. M.
Ghabbour, Hazem A.
El-Emam, Ali A.
Chidan Kumar, C. S.
Fun, Hoong-Kun
5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title_full 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title_fullStr 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title_full_unstemmed 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title_short 5-Propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1H,3H)-dione
title_sort 5-propyl-6-(p-tolyl­sulfan­yl)pyrimidine-2,4(1h,3h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998333/
https://www.ncbi.nlm.nih.gov/pubmed/24764894
http://dx.doi.org/10.1107/S1600536814000749
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