(±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate

In the title hydrate, C(24)H(30)N(2)O(4)·H(2)O, the organic mol­ecule adopts an E conformation with respect to the azomethine double bonds. The cyclo­hexane ring is in a chair conformation. The dihedral angle between benzene rings is 79.6 (2)°. Two intra­molecular O—H⋯N hydrogen bonds are present. I...

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Detalles Bibliográficos
Autores principales: Mohan, Nithya, Sreejith, S. S., Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998335/
https://www.ncbi.nlm.nih.gov/pubmed/24764896
http://dx.doi.org/10.1107/S1600536814000713
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author Mohan, Nithya
Sreejith, S. S.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Mohan, Nithya
Sreejith, S. S.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Mohan, Nithya
collection PubMed
description In the title hydrate, C(24)H(30)N(2)O(4)·H(2)O, the organic mol­ecule adopts an E conformation with respect to the azomethine double bonds. The cyclo­hexane ring is in a chair conformation. The dihedral angle between benzene rings is 79.6 (2)°. Two intra­molecular O—H⋯N hydrogen bonds are present. In the crystal, the components are linked by O–H⋯O hydrogen bonds and weak C—H⋯π inter­actions, generating a three-dimensional supramolecular architecture.
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spelling pubmed-39983352014-04-24 (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate Mohan, Nithya Sreejith, S. S. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrate, C(24)H(30)N(2)O(4)·H(2)O, the organic mol­ecule adopts an E conformation with respect to the azomethine double bonds. The cyclo­hexane ring is in a chair conformation. The dihedral angle between benzene rings is 79.6 (2)°. Two intra­molecular O—H⋯N hydrogen bonds are present. In the crystal, the components are linked by O–H⋯O hydrogen bonds and weak C—H⋯π inter­actions, generating a three-dimensional supramolecular architecture. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998335/ /pubmed/24764896 http://dx.doi.org/10.1107/S1600536814000713 Text en © Mohan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohan, Nithya
Sreejith, S. S.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
(±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title_full (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title_fullStr (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title_full_unstemmed (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title_short (±)-trans-6,6′-Dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
title_sort (±)-trans-6,6′-dieth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenol monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998335/
https://www.ncbi.nlm.nih.gov/pubmed/24764896
http://dx.doi.org/10.1107/S1600536814000713
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AT sithambaresanm trans66diethoxy22cyclohexane12diylbisnitrilomethanylylidenediphenolmonohydrate
AT kurupmrprathapachandra trans66diethoxy22cyclohexane12diylbisnitrilomethanylylidenediphenolmonohydrate

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