Cargando…

N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide

In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the mol­ecule has an L-shaped conformation. In the cryst...

Descripción completa

Detalles Bibliográficos
Autores principales: Sreenivasa, S., Nanjundaswamy, M. S., Sudha, A. G., Pampa, K. J., Lokanath, N. K., Suchetan, P. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998341/
https://www.ncbi.nlm.nih.gov/pubmed/24764902
http://dx.doi.org/10.1107/S1600536814001317
_version_ 1782313341326196736
author Sreenivasa, S.
Nanjundaswamy, M. S.
Sudha, A. G.
Pampa, K. J.
Lokanath, N. K.
Suchetan, P. A.
author_facet Sreenivasa, S.
Nanjundaswamy, M. S.
Sudha, A. G.
Pampa, K. J.
Lokanath, N. K.
Suchetan, P. A.
author_sort Sreenivasa, S.
collection PubMed
description In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the mol­ecule has an L-shaped conformation. In the crystal, the mol­ecules are connected into inversion dimers through pairs of N—H⋯O hydrogen bonds and C—H⋯O inter­actions forming R (2) (2)(8) and R (2) (2)(14) loops, respectively. The dimers are connected by further C—H⋯O inter­actions, thereby forming (100) sheets.
format Online
Article
Text
id pubmed-3998341
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39983412014-04-24 N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide Sreenivasa, S. Nanjundaswamy, M. S. Sudha, A. G. Pampa, K. J. Lokanath, N. K. Suchetan, P. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the mol­ecule has an L-shaped conformation. In the crystal, the mol­ecules are connected into inversion dimers through pairs of N—H⋯O hydrogen bonds and C—H⋯O inter­actions forming R (2) (2)(8) and R (2) (2)(14) loops, respectively. The dimers are connected by further C—H⋯O inter­actions, thereby forming (100) sheets. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998341/ /pubmed/24764902 http://dx.doi.org/10.1107/S1600536814001317 Text en © Sreenivasa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sreenivasa, S.
Nanjundaswamy, M. S.
Sudha, A. G.
Pampa, K. J.
Lokanath, N. K.
Suchetan, P. A.
N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title_full N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title_fullStr N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title_full_unstemmed N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title_short N-(4-Methyl­phenyl­sulfon­yl)-3-nitro­benzamide
title_sort n-(4-methyl­phenyl­sulfon­yl)-3-nitro­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998341/
https://www.ncbi.nlm.nih.gov/pubmed/24764902
http://dx.doi.org/10.1107/S1600536814001317
work_keys_str_mv AT sreenivasas n4methylphenylsulfonyl3nitrobenzamide
AT nanjundaswamyms n4methylphenylsulfonyl3nitrobenzamide
AT sudhaag n4methylphenylsulfonyl3nitrobenzamide
AT pampakj n4methylphenylsulfonyl3nitrobenzamide
AT lokanathnk n4methylphenylsulfonyl3nitrobenzamide
AT suchetanpa n4methylphenylsulfonyl3nitrobenzamide