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N-(4-Methylphenylsulfonyl)-3-nitrobenzamide
In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the molecule has an L-shaped conformation. In the cryst...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998341/ https://www.ncbi.nlm.nih.gov/pubmed/24764902 http://dx.doi.org/10.1107/S1600536814001317 |
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author | Sreenivasa, S. Nanjundaswamy, M. S. Sudha, A. G. Pampa, K. J. Lokanath, N. K. Suchetan, P. A. |
author_facet | Sreenivasa, S. Nanjundaswamy, M. S. Sudha, A. G. Pampa, K. J. Lokanath, N. K. Suchetan, P. A. |
author_sort | Sreenivasa, S. |
collection | PubMed |
description | In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the molecule has an L-shaped conformation. In the crystal, the molecules are connected into inversion dimers through pairs of N—H⋯O hydrogen bonds and C—H⋯O interactions forming R (2) (2)(8) and R (2) (2)(14) loops, respectively. The dimers are connected by further C—H⋯O interactions, thereby forming (100) sheets. |
format | Online Article Text |
id | pubmed-3998341 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39983412014-04-24 N-(4-Methylphenylsulfonyl)-3-nitrobenzamide Sreenivasa, S. Nanjundaswamy, M. S. Sudha, A. G. Pampa, K. J. Lokanath, N. K. Suchetan, P. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and the meta-NO(2) group is syn. The C—S—N—C torsion angle is −65.87 (19)° and the molecule has an L-shaped conformation. In the crystal, the molecules are connected into inversion dimers through pairs of N—H⋯O hydrogen bonds and C—H⋯O interactions forming R (2) (2)(8) and R (2) (2)(14) loops, respectively. The dimers are connected by further C—H⋯O interactions, thereby forming (100) sheets. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998341/ /pubmed/24764902 http://dx.doi.org/10.1107/S1600536814001317 Text en © Sreenivasa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sreenivasa, S. Nanjundaswamy, M. S. Sudha, A. G. Pampa, K. J. Lokanath, N. K. Suchetan, P. A. N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title |
N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title_full |
N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title_fullStr |
N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title_full_unstemmed |
N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title_short |
N-(4-Methylphenylsulfonyl)-3-nitrobenzamide |
title_sort | n-(4-methylphenylsulfonyl)-3-nitrobenzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998341/ https://www.ncbi.nlm.nih.gov/pubmed/24764902 http://dx.doi.org/10.1107/S1600536814001317 |
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