N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(15)H(15)NO(4)S, the dihedral angle between the aromatic rings is 80.81 (1)° and the dihedral angle between the planes defined by the S—N—C=O fragment and the sulfonyl benzene ring is 86.34 (1)°. In the extended structure, dimers related by a crystallographic twofold axis are...

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Autores principales: Sreenivasa, S., Palakshamurthy, B. S., Madankumar, S., Lokanath, N. K., Suchetan, P. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998343/
https://www.ncbi.nlm.nih.gov/pubmed/24764904
http://dx.doi.org/10.1107/S1600536814001354
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author Sreenivasa, S.
Palakshamurthy, B. S.
Madankumar, S.
Lokanath, N. K.
Suchetan, P. A.
author_facet Sreenivasa, S.
Palakshamurthy, B. S.
Madankumar, S.
Lokanath, N. K.
Suchetan, P. A.
author_sort Sreenivasa, S.
collection PubMed
description In the title compound, C(15)H(15)NO(4)S, the dihedral angle between the aromatic rings is 80.81 (1)° and the dihedral angle between the planes defined by the S—N—C=O fragment and the sulfonyl benzene ring is 86.34 (1)°. In the extended structure, dimers related by a crystallographic twofold axis are connected by pairs of both N—H⋯O hydrogen bonds and C—H⋯O inter­actions, which generate R (2) (2)(8) and R (2) (2)(14) loops, respectively. A weak aromatic π–π stacking inter­action is also observed [centroid–centroid separation = 3.7305 (3) Å].
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spelling pubmed-39983432014-04-24 N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide Sreenivasa, S. Palakshamurthy, B. S. Madankumar, S. Lokanath, N. K. Suchetan, P. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)NO(4)S, the dihedral angle between the aromatic rings is 80.81 (1)° and the dihedral angle between the planes defined by the S—N—C=O fragment and the sulfonyl benzene ring is 86.34 (1)°. In the extended structure, dimers related by a crystallographic twofold axis are connected by pairs of both N—H⋯O hydrogen bonds and C—H⋯O inter­actions, which generate R (2) (2)(8) and R (2) (2)(14) loops, respectively. A weak aromatic π–π stacking inter­action is also observed [centroid–centroid separation = 3.7305 (3) Å]. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998343/ /pubmed/24764904 http://dx.doi.org/10.1107/S1600536814001354 Text en © Sreenivasa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sreenivasa, S.
Palakshamurthy, B. S.
Madankumar, S.
Lokanath, N. K.
Suchetan, P. A.
N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title_full N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title_fullStr N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title_short N-(4-Meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
title_sort n-(4-meth­oxy­benzo­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998343/
https://www.ncbi.nlm.nih.gov/pubmed/24764904
http://dx.doi.org/10.1107/S1600536814001354
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