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2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one
The title molecule, C(15)H(12)ClNO, features a dihydroquinolin-4(1H)-one moiety attached to a chlorobenzene ring. The heterocyclic ring has a half-chair conformation with the methine C atom lying 0.574 (3) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0240 Å). The dihedral...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998350/ https://www.ncbi.nlm.nih.gov/pubmed/24764911 http://dx.doi.org/10.1107/S1600536814001548 |
Sumario: | The title molecule, C(15)H(12)ClNO, features a dihydroquinolin-4(1H)-one moiety attached to a chlorobenzene ring. The heterocyclic ring has a half-chair conformation with the methine C atom lying 0.574 (3) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0240 Å). The dihedral angles between the terminal benzene rings is 77.53 (9)°, indicating a significant twist in the molecule. In the crystal, supramolecular zigzag chains along the c-axis direction are sustained by N—H⋯O hydrogen bonds. These are connected into double chains by C—H⋯π interactions. |
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