2-(4,5-Di­chloro-2-nitro­phen­yl)-4-meth­oxy-3-methyl-9-phenyl­sulfon­yl-9H-carbazole

In the title compound, C(26)H(18)Cl(2)N(2)O(5)S, the carbazole ring system is essentially planar with a maximum deviation of 0.0498 (16) Å for the N atom. The carbazole ring system is almost orthogonal to the phenyl­sulfonyl and di­chloro-substituted nitro­phenyl rings, making dihedral angles of 84....

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Detalles Bibliográficos
Autores principales: Narayanan, P., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998356/
https://www.ncbi.nlm.nih.gov/pubmed/24764917
http://dx.doi.org/10.1107/S1600536814001342
Descripción
Sumario:In the title compound, C(26)H(18)Cl(2)N(2)O(5)S, the carbazole ring system is essentially planar with a maximum deviation of 0.0498 (16) Å for the N atom. The carbazole ring system is almost orthogonal to the phenyl­sulfonyl and di­chloro-substituted nitro­phenyl rings, making dihedral angles of 84.23 (7) and 85.46 (12)°, respectively. The mol­ecular structure features intra­molecular C—H⋯O inter­actions, which generate two S(6) ring motifs. In the crystal, mol­ecules are linked by C—Cl⋯O halogen bonds [3.016 (3) Å, 166.63 (5)°], which generate infinite C(8) chains running parallel to [010].

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