Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate

In the title compound, C(18)H(22)N(2)O(4)S(2), the 2H-chromene ring system is essentially planar (r.m.s. deviation = 0.012 Å). The mol­ecular conformation is stabilized by a C—H⋯O hydrogen bond. In the crystal, N—H⋯S and C—H⋯O hydrogen bonds occur, the former enclosing an R (2) (2)(22) ring motif, a...

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Autores principales: Roopashree, K. R., Kumar, K. Mahesh, Anitha, B. R., Ravi, A. J., Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998360/
https://www.ncbi.nlm.nih.gov/pubmed/24764921
http://dx.doi.org/10.1107/S1600536814001706
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author Roopashree, K. R.
Kumar, K. Mahesh
Anitha, B. R.
Ravi, A. J.
Devarajegowda, H. C.
author_facet Roopashree, K. R.
Kumar, K. Mahesh
Anitha, B. R.
Ravi, A. J.
Devarajegowda, H. C.
author_sort Roopashree, K. R.
collection PubMed
description In the title compound, C(18)H(22)N(2)O(4)S(2), the 2H-chromene ring system is essentially planar (r.m.s. deviation = 0.012 Å). The mol­ecular conformation is stabilized by a C—H⋯O hydrogen bond. In the crystal, N—H⋯S and C—H⋯O hydrogen bonds occur, the former enclosing an R (2) (2)(22) ring motif, and lead to the formation of a two-dimensional slab-like network lying parallel to (10-1). π–π inter­actions are observed between inversion-related aromatic rings [shortest centroid–centroid distance = 3.6300 (11) Å].
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spelling pubmed-39983602014-04-24 Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate Roopashree, K. R. Kumar, K. Mahesh Anitha, B. R. Ravi, A. J. Devarajegowda, H. C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(22)N(2)O(4)S(2), the 2H-chromene ring system is essentially planar (r.m.s. deviation = 0.012 Å). The mol­ecular conformation is stabilized by a C—H⋯O hydrogen bond. In the crystal, N—H⋯S and C—H⋯O hydrogen bonds occur, the former enclosing an R (2) (2)(22) ring motif, and lead to the formation of a two-dimensional slab-like network lying parallel to (10-1). π–π inter­actions are observed between inversion-related aromatic rings [shortest centroid–centroid distance = 3.6300 (11) Å]. International Union of Crystallography 2014-01-29 /pmc/articles/PMC3998360/ /pubmed/24764921 http://dx.doi.org/10.1107/S1600536814001706 Text en © Roopashree et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Roopashree, K. R.
Kumar, K. Mahesh
Anitha, B. R.
Ravi, A. J.
Devarajegowda, H. C.
Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title_full Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title_fullStr Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title_full_unstemmed Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title_short Ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2H-chromen-7-yl)carbamate
title_sort ethyl (4-{[(di­ethyl­carbamo­thio­yl)sulfan­yl]meth­yl}-2-oxo-2h-chromen-7-yl)carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998360/
https://www.ncbi.nlm.nih.gov/pubmed/24764921
http://dx.doi.org/10.1107/S1600536814001706
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AT raviaj ethyl4diethylcarbamothioylsulfanylmethyl2oxo2hchromen7ylcarbamate
AT devarajegowdahc ethyl4diethylcarbamothioylsulfanylmethyl2oxo2hchromen7ylcarbamate

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