N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide

In the title compound, C(14)H(21)NO, the conformation across the N—C(O) bond is syn-periplanar, the C—N—C—C torsion being −5.9 (5)°. The atoms of the ethyl group attached to the N atom are disordered over two sets of sites with occupancy ratios of 0.65 (2):0.35 (2) (CH(2)) and 0.689 (14):0.311 (14)...

Descripción completa

Detalles Bibliográficos
Autores principales: Palakshamurthy, B. S., Suchetan, P. A., Sreenivasa, S, Lokanath, N. K., Madhu Chakrapani Rao, T
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998362/
https://www.ncbi.nlm.nih.gov/pubmed/24764923
http://dx.doi.org/10.1107/S1600536814001718
_version_ 1782313346046885888
author Palakshamurthy, B. S.
Suchetan, P. A.
Sreenivasa, S
Lokanath, N. K.
Madhu Chakrapani Rao, T
author_facet Palakshamurthy, B. S.
Suchetan, P. A.
Sreenivasa, S
Lokanath, N. K.
Madhu Chakrapani Rao, T
author_sort Palakshamurthy, B. S.
collection PubMed
description In the title compound, C(14)H(21)NO, the conformation across the N—C(O) bond is syn-periplanar, the C—N—C—C torsion being −5.9 (5)°. The atoms of the ethyl group attached to the N atom are disordered over two sets of sites with occupancy ratios of 0.65 (2):0.35 (2) (CH(2)) and 0.689 (14):0.311 (14) (CH(3))are linked by very weak C—H⋯O inter­actions forming C(8) chains along [001]. C—H⋯π inter­actions link the mol­ecules along the c-axis direction.
format Online
Article
Text
id pubmed-3998362
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39983622014-04-24 N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide Palakshamurthy, B. S. Suchetan, P. A. Sreenivasa, S Lokanath, N. K. Madhu Chakrapani Rao, T Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(21)NO, the conformation across the N—C(O) bond is syn-periplanar, the C—N—C—C torsion being −5.9 (5)°. The atoms of the ethyl group attached to the N atom are disordered over two sets of sites with occupancy ratios of 0.65 (2):0.35 (2) (CH(2)) and 0.689 (14):0.311 (14) (CH(3))are linked by very weak C—H⋯O inter­actions forming C(8) chains along [001]. C—H⋯π inter­actions link the mol­ecules along the c-axis direction. International Union of Crystallography 2014-01-29 /pmc/articles/PMC3998362/ /pubmed/24764923 http://dx.doi.org/10.1107/S1600536814001718 Text en © Palakshamurthy et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Palakshamurthy, B. S.
Suchetan, P. A.
Sreenivasa, S
Lokanath, N. K.
Madhu Chakrapani Rao, T
N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title_full N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title_fullStr N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title_full_unstemmed N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title_short N-Ethyl-2,2-dimethyl-N-(3-methyl­phen­yl)propanamide
title_sort n-ethyl-2,2-dimethyl-n-(3-methyl­phen­yl)propanamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998362/
https://www.ncbi.nlm.nih.gov/pubmed/24764923
http://dx.doi.org/10.1107/S1600536814001718
work_keys_str_mv AT palakshamurthybs nethyl22dimethyln3methylphenylpropanamide
AT suchetanpa nethyl22dimethyln3methylphenylpropanamide
AT sreenivasas nethyl22dimethyln3methylphenylpropanamide
AT lokanathnk nethyl22dimethyln3methylphenylpropanamide
AT madhuchakrapaniraot nethyl22dimethyln3methylphenylpropanamide

Ejemplares similares