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2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of t...

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Autores principales: Narayanan, P., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998368/
https://www.ncbi.nlm.nih.gov/pubmed/24764929
http://dx.doi.org/10.1107/S1600536814001809
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author Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_facet Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_sort Narayanan, P.
collection PubMed
description In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of the meth­oxy group deviates by 0.186 (1) Å from the adjacent carbazole moiety. The phenyl­sulfonyl group forms intra­molecular C—H⋯O bonds between sulfone O atoms and the carbazole moiety, resulting in two S(6) rings. In the crystal, the nitrated benzene rings are linked via C—H⋯O inter­actions forming infinite C(7) chains along [100]. The crystal packing is also characterized by C—H⋯π inter­actions, which result in inversion dimers.
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spelling pubmed-39983682014-04-24 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of the meth­oxy group deviates by 0.186 (1) Å from the adjacent carbazole moiety. The phenyl­sulfonyl group forms intra­molecular C—H⋯O bonds between sulfone O atoms and the carbazole moiety, resulting in two S(6) rings. In the crystal, the nitrated benzene rings are linked via C—H⋯O inter­actions forming infinite C(7) chains along [100]. The crystal packing is also characterized by C—H⋯π inter­actions, which result in inversion dimers. International Union of Crystallography 2014-01-31 /pmc/articles/PMC3998368/ /pubmed/24764929 http://dx.doi.org/10.1107/S1600536814001809 Text en © Narayanan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Narayanan, P.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_fullStr 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full_unstemmed 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_short 2-(4-Chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_sort 2-(4-chloro-2-nitro­phen­yl)-4-meth­oxy-9-phenyl­sulfonyl-9h-carbazole-3-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998368/
https://www.ncbi.nlm.nih.gov/pubmed/24764929
http://dx.doi.org/10.1107/S1600536814001809
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