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2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde
In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998368/ https://www.ncbi.nlm.nih.gov/pubmed/24764929 http://dx.doi.org/10.1107/S1600536814001809 |
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author | Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. |
author_facet | Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. |
author_sort | Narayanan, P. |
collection | PubMed |
description | In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of the methoxy group deviates by 0.186 (1) Å from the adjacent carbazole moiety. The phenylsulfonyl group forms intramolecular C—H⋯O bonds between sulfone O atoms and the carbazole moiety, resulting in two S(6) rings. In the crystal, the nitrated benzene rings are linked via C—H⋯O interactions forming infinite C(7) chains along [100]. The crystal packing is also characterized by C—H⋯π interactions, which result in inversion dimers. |
format | Online Article Text |
id | pubmed-3998368 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39983682014-04-24 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the sterically hindered title compound, C(26)H(17)ClN(2)O(6)S, the carbazole ring has a maximum deviation from planarity of 0.067 (4) Å for the C atom connected to the aldehyde group. The carbazole moiety forms a dihedral angle of 72.8 (1)° with the nitro-substituted benzene ring. The O atom of the methoxy group deviates by 0.186 (1) Å from the adjacent carbazole moiety. The phenylsulfonyl group forms intramolecular C—H⋯O bonds between sulfone O atoms and the carbazole moiety, resulting in two S(6) rings. In the crystal, the nitrated benzene rings are linked via C—H⋯O interactions forming infinite C(7) chains along [100]. The crystal packing is also characterized by C—H⋯π interactions, which result in inversion dimers. International Union of Crystallography 2014-01-31 /pmc/articles/PMC3998368/ /pubmed/24764929 http://dx.doi.org/10.1107/S1600536814001809 Text en © Narayanan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Narayanan, P. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title | 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_full | 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_fullStr | 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_full_unstemmed | 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_short | 2-(4-Chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde |
title_sort | 2-(4-chloro-2-nitrophenyl)-4-methoxy-9-phenylsulfonyl-9h-carbazole-3-carbaldehyde |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998368/ https://www.ncbi.nlm.nih.gov/pubmed/24764929 http://dx.doi.org/10.1107/S1600536814001809 |
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