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[2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate
The asymmetric unit of the title hydrated salt, C(24)H(35)N(2)O(5) (+)·Cl(−)·2H(2)O, contains one organic cation that has its protonation site at the amine function, one chloride anion and two lattice water molecules. In the crystal, one pair of lattice water molecules and two chloride anions form...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998369/ https://www.ncbi.nlm.nih.gov/pubmed/24764930 http://dx.doi.org/10.1107/S1600536814001998 |
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author | Saidov, Abdusalom Sh. Turgunov, Kambarali K. |
author_facet | Saidov, Abdusalom Sh. Turgunov, Kambarali K. |
author_sort | Saidov, Abdusalom Sh. |
collection | PubMed |
description | The asymmetric unit of the title hydrated salt, C(24)H(35)N(2)O(5) (+)·Cl(−)·2H(2)O, contains one organic cation that has its protonation site at the amine function, one chloride anion and two lattice water molecules. In the crystal, one pair of lattice water molecules and two chloride anions form a four-membered centrosymmetric hydrogen-bond cycle. In addition, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds involving the N—H groups, the water molecules and the C=O group are observed. As a result, a hydrogen-bonded layer parallel to (100) is formed. The thickness of such a layer corresponds to the length of the a axis [21.977 (3) Å]. |
format | Online Article Text |
id | pubmed-3998369 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39983692014-04-24 [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate Saidov, Abdusalom Sh. Turgunov, Kambarali K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title hydrated salt, C(24)H(35)N(2)O(5) (+)·Cl(−)·2H(2)O, contains one organic cation that has its protonation site at the amine function, one chloride anion and two lattice water molecules. In the crystal, one pair of lattice water molecules and two chloride anions form a four-membered centrosymmetric hydrogen-bond cycle. In addition, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds involving the N—H groups, the water molecules and the C=O group are observed. As a result, a hydrogen-bonded layer parallel to (100) is formed. The thickness of such a layer corresponds to the length of the a axis [21.977 (3) Å]. International Union of Crystallography 2014-01-31 /pmc/articles/PMC3998369/ /pubmed/24764930 http://dx.doi.org/10.1107/S1600536814001998 Text en © Saidov and Turgunov 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saidov, Abdusalom Sh. Turgunov, Kambarali K. [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title | [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title_full | [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title_fullStr | [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title_full_unstemmed | [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title_short | [2-(3,4-Dimethoxyphenyl)ethyl](3-{N-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
title_sort | [2-(3,4-dimethoxyphenyl)ethyl](3-{n-[2-(3,4-dimethoxyphenyl)ethyl]carbamoyl}propyl)azanium chloride dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998369/ https://www.ncbi.nlm.nih.gov/pubmed/24764930 http://dx.doi.org/10.1107/S1600536814001998 |
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