Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate

In the title compound, C(25)H(23)NO(4), the pyran ring of the chroman moiety has an envelope conformation with the methyl­ene C atom as the flap. The isoxazole ring has a twist conformation on the O—C bond. The dihedral angle between their mean planes is 57.87 (9)°. The attached phenyl and benzene r...

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Autores principales: Raghuvarman, B., Srinivasan, J., Bakthadoss, M., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998385/
https://www.ncbi.nlm.nih.gov/pubmed/24764992
http://dx.doi.org/10.1107/S1600536814002438
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author Raghuvarman, B.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
author_facet Raghuvarman, B.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
author_sort Raghuvarman, B.
collection PubMed
description In the title compound, C(25)H(23)NO(4), the pyran ring of the chroman moiety has an envelope conformation with the methyl­ene C atom as the flap. The isoxazole ring has a twist conformation on the O—C bond. The dihedral angle between their mean planes is 57.87 (9)°. The attached phenyl and benzene rings are twisted away from its mean plane by 56.19 (10) and 50.57 (10)°, respectively. These two rings are normal to each other, subtending a dihedral angle of 89.2 (1)°. In the crystal, there are no classical hydrogen bonds; the mol­ecules are linked via C—H⋯π inter­actions, forming a two-dimensional network lying parallel to (10-1).
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spelling pubmed-39983852014-04-24 Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate Raghuvarman, B. Srinivasan, J. Bakthadoss, M. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(23)NO(4), the pyran ring of the chroman moiety has an envelope conformation with the methyl­ene C atom as the flap. The isoxazole ring has a twist conformation on the O—C bond. The dihedral angle between their mean planes is 57.87 (9)°. The attached phenyl and benzene rings are twisted away from its mean plane by 56.19 (10) and 50.57 (10)°, respectively. These two rings are normal to each other, subtending a dihedral angle of 89.2 (1)°. In the crystal, there are no classical hydrogen bonds; the mol­ecules are linked via C—H⋯π inter­actions, forming a two-dimensional network lying parallel to (10-1). International Union of Crystallography 2014-02-12 /pmc/articles/PMC3998385/ /pubmed/24764992 http://dx.doi.org/10.1107/S1600536814002438 Text en © Raghuvarman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raghuvarman, B.
Srinivasan, J.
Bakthadoss, M.
Aravindhan, S.
Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title_full Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title_fullStr Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title_full_unstemmed Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title_short Methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxyl­ate
title_sort methyl 1-phenyl-3-p-tolyl-1,9b-di­hydro-3h-chromeno[4,3-c]isoxazole-3a(4h)-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998385/
https://www.ncbi.nlm.nih.gov/pubmed/24764992
http://dx.doi.org/10.1107/S1600536814002438
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AT bakthadossm methyl1phenyl3ptolyl19bdihydro3hchromeno43cisoxazole3a4hcarboxylate
AT aravindhans methyl1phenyl3ptolyl19bdihydro3hchromeno43cisoxazole3a4hcarboxylate

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