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Bis(acetato-κO)bis(thiourea-κS)cobalt(II)
The title compound, [Co(CH(3)COO)(2)(CH(4)N(2)S)(2)], is isotypic with the corresponding Zn(II) complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H ato...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998386/ https://www.ncbi.nlm.nih.gov/pubmed/24764944 http://dx.doi.org/10.1107/S1600536814002074 |
| _version_ | 1782313349668667392 |
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| author | Lutz, Martin |
| author_facet | Lutz, Martin |
| author_sort | Lutz, Martin |
| collection | PubMed |
| description | The title compound, [Co(CH(3)COO)(2)(CH(4)N(2)S)(2)], is isotypic with the corresponding Zn(II) complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N—H⋯O and N—H⋯S hydrogen bonds, leading to a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3998386 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39983862014-04-24 Bis(acetato-κO)bis(thiourea-κS)cobalt(II) Lutz, Martin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(CH(3)COO)(2)(CH(4)N(2)S)(2)], is isotypic with the corresponding Zn(II) complex. The metal atom is in a distorted tetrahedral coordination environment with the two S atoms from two thiourea ligands and two O atoms from two acetate anions as the coordinating atoms. All H atoms of the thiourea ligands are involved in N—H⋯O and N—H⋯S hydrogen bonds, leading to a three-dimensional network. International Union of Crystallography 2014-02-05 /pmc/articles/PMC3998386/ /pubmed/24764944 http://dx.doi.org/10.1107/S1600536814002074 Text en © Martin Lutz 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lutz, Martin Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title | Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title_full | Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title_fullStr | Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title_full_unstemmed | Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title_short | Bis(acetato-κO)bis(thiourea-κS)cobalt(II) |
| title_sort | bis(acetato-κo)bis(thiourea-κs)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998386/ https://www.ncbi.nlm.nih.gov/pubmed/24764944 http://dx.doi.org/10.1107/S1600536814002074 |
| work_keys_str_mv | AT lutzmartin bisacetatokobisthioureakscobaltii |