2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate

In the title hydrated molecular salt, C(22)H(18)BrN(4)S(+)·Br(−)·H(2)O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thia­zole ring. In the crystal, mol­ecules are linked into chains running parallel to the a axis by association of the bromide ions and t...

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Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, Abd El-Alaziz, Ahmed T., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998394/
https://www.ncbi.nlm.nih.gov/pubmed/24765025
http://dx.doi.org/10.1107/S160053681400347X
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author Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abd El-Alaziz, Ahmed T.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abd El-Alaziz, Ahmed T.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description In the title hydrated molecular salt, C(22)H(18)BrN(4)S(+)·Br(−)·H(2)O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thia­zole ring. In the crystal, mol­ecules are linked into chains running parallel to the a axis by association of the bromide ions and the water mol­ecules of crystallization with the cations via N—H⋯O, O—H⋯Br, C—H⋯N and C—H⋯Br hydrogen-bonding inter­actions. C—H⋯π and C—Br⋯π [3.7426 (11) Å, 161.73 (7)°] inter­actions are also observed, forming infinite chains extending along the b-axis direction.
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spelling pubmed-39983942014-04-24 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abd El-Alaziz, Ahmed T. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated molecular salt, C(22)H(18)BrN(4)S(+)·Br(−)·H(2)O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thia­zole ring. In the crystal, mol­ecules are linked into chains running parallel to the a axis by association of the bromide ions and the water mol­ecules of crystallization with the cations via N—H⋯O, O—H⋯Br, C—H⋯N and C—H⋯Br hydrogen-bonding inter­actions. C—H⋯π and C—Br⋯π [3.7426 (11) Å, 161.73 (7)°] inter­actions are also observed, forming infinite chains extending along the b-axis direction. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998394/ /pubmed/24765025 http://dx.doi.org/10.1107/S160053681400347X Text en © Mague et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abd El-Alaziz, Ahmed T.
Albayati, Mustafa R.
2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title_full 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title_fullStr 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title_full_unstemmed 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title_short 2-((1E)-1-{2-[(2Z)-4-(4-Bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
title_sort 2-((1e)-1-{2-[(2z)-4-(4-bromo­phen­yl)-3-phenyl-2,3-di­hydro-1,3-thia­zol-2-yl­idene]hydrazin-1-yl­idene}eth­yl)pyridin-1-ium bromide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998394/
https://www.ncbi.nlm.nih.gov/pubmed/24765025
http://dx.doi.org/10.1107/S160053681400347X
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