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Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane
In the title compound, C(40)H(76)Si, the Si atom is located on a special position of site symmetry -4. Thus, there is just a quarter of a molecule in the asymmetric unit. The C=C double bonds exhibit a trans configuration. The Si atom and the tert-butyl group are located on the same side of the pla...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998395/ https://www.ncbi.nlm.nih.gov/pubmed/24765057 http://dx.doi.org/10.1107/S1600536814004322 |
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author | Meyer-Wegner, Frank Bolte, Michael Lerner, Hans-Wolfram |
author_facet | Meyer-Wegner, Frank Bolte, Michael Lerner, Hans-Wolfram |
author_sort | Meyer-Wegner, Frank |
collection | PubMed |
description | In the title compound, C(40)H(76)Si, the Si atom is located on a special position of site symmetry -4. Thus, there is just a quarter of a molecule in the asymmetric unit. The C=C double bonds exhibit a trans configuration. The Si atom and the tert-butyl group are located on the same side of the plane formed by the C=C double bond and its four substituents. The crystal packing shows no short contacts between the molecules and despite the low crystal density (0.980 Mg m(−3)), there are no significant voids in the structure. |
format | Online Article Text |
id | pubmed-3998395 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39983952014-04-24 Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane Meyer-Wegner, Frank Bolte, Michael Lerner, Hans-Wolfram Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(40)H(76)Si, the Si atom is located on a special position of site symmetry -4. Thus, there is just a quarter of a molecule in the asymmetric unit. The C=C double bonds exhibit a trans configuration. The Si atom and the tert-butyl group are located on the same side of the plane formed by the C=C double bond and its four substituents. The crystal packing shows no short contacts between the molecules and despite the low crystal density (0.980 Mg m(−3)), there are no significant voids in the structure. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998395/ /pubmed/24765057 http://dx.doi.org/10.1107/S1600536814004322 Text en © Meyer-Wegner et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Meyer-Wegner, Frank Bolte, Michael Lerner, Hans-Wolfram Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title | Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title_full | Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title_fullStr | Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title_full_unstemmed | Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title_short | Tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
title_sort | tetrakis(2,3,5,5-tetramethylhexen-2-yl)silane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998395/ https://www.ncbi.nlm.nih.gov/pubmed/24765057 http://dx.doi.org/10.1107/S1600536814004322 |
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