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2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro­phenyl ring. It is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 88.45...

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Detalles Bibliográficos
Autores principales: Gopinath, S., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998398/
https://www.ncbi.nlm.nih.gov/pubmed/24764987
http://dx.doi.org/10.1107/S1600536814002633
Descripción
Sumario:In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro­phenyl ring. It is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 88.45 (8) and 79.26 (7)°, respectively. The mol­ecular structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol­ecules are linked by two C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, so forming a two-dimensional network lying parallel to (001). There are also supra­molecular R (4) (3)(28) graph-set ring motifs enclosed within these networks.