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2-(4-Fluoro-2-nitrophenyl)-4-hydroxy-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde
In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitrophenyl ring. It is almost orthogonal to the phenylsulfonyl and nitrophenyl rings, making dihedral angles of 88.45...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998398/ https://www.ncbi.nlm.nih.gov/pubmed/24764987 http://dx.doi.org/10.1107/S1600536814002633 |
Sumario: | In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitrophenyl ring. It is almost orthogonal to the phenylsulfonyl and nitrophenyl rings, making dihedral angles of 88.45 (8) and 79.26 (7)°, respectively. The molecular structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, molecules are linked by two C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, so forming a two-dimensional network lying parallel to (001). There are also supramolecular R (4) (3)(28) graph-set ring motifs enclosed within these networks. |
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