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2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro­phenyl ring. It is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 88.45...

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Autores principales: Gopinath, S., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998398/
https://www.ncbi.nlm.nih.gov/pubmed/24764987
http://dx.doi.org/10.1107/S1600536814002633
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author Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_facet Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_sort Gopinath, S.
collection PubMed
description In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro­phenyl ring. It is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 88.45 (8) and 79.26 (7)°, respectively. The mol­ecular structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol­ecules are linked by two C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, so forming a two-dimensional network lying parallel to (001). There are also supra­molecular R (4) (3)(28) graph-set ring motifs enclosed within these networks.
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spelling pubmed-39983982014-04-24 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde Gopinath, S. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(15)FN(2)O(6)S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro­phenyl ring. It is almost orthogonal to the phenyl­sulfonyl and nitro­phenyl rings, making dihedral angles of 88.45 (8) and 79.26 (7)°, respectively. The mol­ecular structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol­ecules are linked by two C—H⋯O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, so forming a two-dimensional network lying parallel to (001). There are also supra­molecular R (4) (3)(28) graph-set ring motifs enclosed within these networks. International Union of Crystallography 2014-02-12 /pmc/articles/PMC3998398/ /pubmed/24764987 http://dx.doi.org/10.1107/S1600536814002633 Text en © Gopinath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_fullStr 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_full_unstemmed 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_short 2-(4-Fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9H-carbazole-3-carbaldehyde
title_sort 2-(4-fluoro-2-nitro­phen­yl)-4-hy­droxy-9-phenyl­sulfonyl-9h-carbazole-3-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998398/
https://www.ncbi.nlm.nih.gov/pubmed/24764987
http://dx.doi.org/10.1107/S1600536814002633
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