Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)

The title compound, [HP(CH(3))(3)][IrCl(4){(H(3)C)(3)P}(2)], consists of a tri­methyl­phospho­nium cation and a tetra­chlorido­bis­(tri­methyl­phosphane)iridate(III) anion. The anion has an octa­hedral arrangement of ligands, with the tri­methyl­phosphane groups occupying trans positions. The Ir(III...

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Detalles Bibliográficos
Autores principales: Berg, Michael A., Davidson, Jesse, Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998401/
https://www.ncbi.nlm.nih.gov/pubmed/24764937
http://dx.doi.org/10.1107/S160053681400350X
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author Berg, Michael A.
Davidson, Jesse
Merola, Joseph S.
author_facet Berg, Michael A.
Davidson, Jesse
Merola, Joseph S.
author_sort Berg, Michael A.
collection PubMed
description The title compound, [HP(CH(3))(3)][IrCl(4){(H(3)C)(3)P}(2)], consists of a tri­methyl­phospho­nium cation and a tetra­chlorido­bis­(tri­methyl­phosphane)iridate(III) anion. The anion has an octa­hedral arrangement of ligands, with the tri­methyl­phosphane groups occupying trans positions. The Ir(III) atom sits on an inversion center with one P(CH(3))(3) ligand and two chloride ligands in the asymmetric unit. The tri­methyl­phospho­nium cation is disordered about a twofold rotation axis. The title compound is the first structurally characterized tetra­chlorido­bis­(phosphane)iridate complex.
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spelling pubmed-39984012014-04-24 Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III) Berg, Michael A. Davidson, Jesse Merola, Joseph S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [HP(CH(3))(3)][IrCl(4){(H(3)C)(3)P}(2)], consists of a tri­methyl­phospho­nium cation and a tetra­chlorido­bis­(tri­methyl­phosphane)iridate(III) anion. The anion has an octa­hedral arrangement of ligands, with the tri­methyl­phosphane groups occupying trans positions. The Ir(III) atom sits on an inversion center with one P(CH(3))(3) ligand and two chloride ligands in the asymmetric unit. The tri­methyl­phospho­nium cation is disordered about a twofold rotation axis. The title compound is the first structurally characterized tetra­chlorido­bis­(phosphane)iridate complex. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998401/ /pubmed/24764937 http://dx.doi.org/10.1107/S160053681400350X Text en © Berg et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Berg, Michael A.
Davidson, Jesse
Merola, Joseph S.
Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title_full Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title_fullStr Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title_full_unstemmed Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title_short Tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κP)iridate(III)
title_sort tri­methyl­phospho­nium trans-tetra­chlorido­bis­(tri­methyl­phosphane-κp)iridate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998401/
https://www.ncbi.nlm.nih.gov/pubmed/24764937
http://dx.doi.org/10.1107/S160053681400350X
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