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2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
The title compound, C(22)H(20)Br(2)N(2)S, was synthesized under solvent-free conditions. The molecule shows crystallographic C (2) symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998402/ https://www.ncbi.nlm.nih.gov/pubmed/24765036 http://dx.doi.org/10.1107/S1600536814003651 |
Sumario: | The title compound, C(22)H(20)Br(2)N(2)S, was synthesized under solvent-free conditions. The molecule shows crystallographic C (2) symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted conformation. The dihedral angle between the thiophene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, molecules are arranged in a chevron-like pattern, without any significant intermolecular interactions. |
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