2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene

The title compound, C(22)H(20)Br(2)N(2)S, was synthesized under solvent-free conditions. The mol­ecule shows crystallographic C (2) symmetry, with the S atom of the central thio­phene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the mol­ecule has...

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Detalles Bibliográficos
Autores principales: Mendoza, Angel, Bernès, Sylvain, Hernández-Téllez, Guadalupe, Portillo-Moreno, Oscar, Gutiérrez, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998402/
https://www.ncbi.nlm.nih.gov/pubmed/24765036
http://dx.doi.org/10.1107/S1600536814003651
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author Mendoza, Angel
Bernès, Sylvain
Hernández-Téllez, Guadalupe
Portillo-Moreno, Oscar
Gutiérrez, René
author_facet Mendoza, Angel
Bernès, Sylvain
Hernández-Téllez, Guadalupe
Portillo-Moreno, Oscar
Gutiérrez, René
author_sort Mendoza, Angel
collection PubMed
description The title compound, C(22)H(20)Br(2)N(2)S, was synthesized under solvent-free conditions. The mol­ecule shows crystallographic C (2) symmetry, with the S atom of the central thio­phene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the mol­ecule has a twisted conformation. The dihedral angle between the thio­phene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, mol­ecules are arranged in a chevron-like pattern, without any significant inter­molecular inter­actions.
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spelling pubmed-39984022014-04-24 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene Mendoza, Angel Bernès, Sylvain Hernández-Téllez, Guadalupe Portillo-Moreno, Oscar Gutiérrez, René Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)Br(2)N(2)S, was synthesized under solvent-free conditions. The mol­ecule shows crystallographic C (2) symmetry, with the S atom of the central thio­phene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the mol­ecule has a twisted conformation. The dihedral angle between the thio­phene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, mol­ecules are arranged in a chevron-like pattern, without any significant inter­molecular inter­actions. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998402/ /pubmed/24765036 http://dx.doi.org/10.1107/S1600536814003651 Text en © Mendoza et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mendoza, Angel
Bernès, Sylvain
Hernández-Téllez, Guadalupe
Portillo-Moreno, Oscar
Gutiérrez, René
2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_full 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_fullStr 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_full_unstemmed 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_short 2,5-Bis{[(−)-(S)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
title_sort 2,5-bis{[(−)-(s)-1-(4-bromo­phen­yl)eth­yl]imino­meth­yl}thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998402/
https://www.ncbi.nlm.nih.gov/pubmed/24765036
http://dx.doi.org/10.1107/S1600536814003651
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