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3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan

In the title compound, C(21)H(21)BrO(2)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean plane [r.m.s. deviation = 0.178 (2) Å] of the benzo­furan ring system and the mean plane of the 3-bromo­phenyl ring is 86.52 (6)°. In the crystal, mol­ecules are linked by...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998404/
https://www.ncbi.nlm.nih.gov/pubmed/24765010
http://dx.doi.org/10.1107/S160053681400316X
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(21)H(21)BrO(2)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean plane [r.m.s. deviation = 0.178 (2) Å] of the benzo­furan ring system and the mean plane of the 3-bromo­phenyl ring is 86.52 (6)°. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π hydrogen bonds, and by a slipped π–π inter­action between the furan rings of neighbouring mol­ecules [centroid–centroid distance = 3.518 (3) Å, inter­planar distance = 3.471 (3) Å and slippage = 0.573 (3) Å], resulting in a three-dimensional network.
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spelling pubmed-39984042014-04-24 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)BrO(2)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean plane [r.m.s. deviation = 0.178 (2) Å] of the benzo­furan ring system and the mean plane of the 3-bromo­phenyl ring is 86.52 (6)°. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π hydrogen bonds, and by a slipped π–π inter­action between the furan rings of neighbouring mol­ecules [centroid–centroid distance = 3.518 (3) Å, inter­planar distance = 3.471 (3) Å and slippage = 0.573 (3) Å], resulting in a three-dimensional network. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998404/ /pubmed/24765010 http://dx.doi.org/10.1107/S160053681400316X Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_full 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_fullStr 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_full_unstemmed 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_short 3-(3-Bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_sort 3-(3-bromo­phenyl­sulfin­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998404/
https://www.ncbi.nlm.nih.gov/pubmed/24765010
http://dx.doi.org/10.1107/S160053681400316X
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