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trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)

In the title compound, [Cu(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)], the Cu(II) ion, located on an inversion center, exhibits an octa­hedral coordination geometry. The equatorial plane is defined by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two...

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Autores principales: Pache, Aroa, Iturrospe, Amaia, San Felices, Leire, Reinoso, Santiago, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998405/
https://www.ncbi.nlm.nih.gov/pubmed/24764943
http://dx.doi.org/10.1107/S1600536814004334
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author Pache, Aroa
Iturrospe, Amaia
San Felices, Leire
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_facet Pache, Aroa
Iturrospe, Amaia
San Felices, Leire
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
author_sort Pache, Aroa
collection PubMed
description In the title compound, [Cu(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)], the Cu(II) ion, located on an inversion center, exhibits an octa­hedral coordination geometry. The equatorial plane is defined by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds between the water mol­ecules and the noncoordinating carboxyl­ate O atoms, forming layers parallel to the bc plane. The layers are stacked along the a axis by further O—H⋯O hydrogen bonds between the water mol­ecules and the coordinating carboxyl­ate O atoms. Weak C—H⋯O hydrogen bonds are also observed between the pyridazine rings and the water mol­ecules and between the pyridazine rings and the non-coordinating carboxyl­ate O atoms.
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spelling pubmed-39984052014-04-24 trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II) Pache, Aroa Iturrospe, Amaia San Felices, Leire Reinoso, Santiago Gutiérrez-Zorrilla, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)], the Cu(II) ion, located on an inversion center, exhibits an octa­hedral coordination geometry. The equatorial plane is defined by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds between the water mol­ecules and the noncoordinating carboxyl­ate O atoms, forming layers parallel to the bc plane. The layers are stacked along the a axis by further O—H⋯O hydrogen bonds between the water mol­ecules and the coordinating carboxyl­ate O atoms. Weak C—H⋯O hydrogen bonds are also observed between the pyridazine rings and the water mol­ecules and between the pyridazine rings and the non-coordinating carboxyl­ate O atoms. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998405/ /pubmed/24764943 http://dx.doi.org/10.1107/S1600536814004334 Text en © Pache et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pache, Aroa
Iturrospe, Amaia
San Felices, Leire
Reinoso, Santiago
Gutiérrez-Zorrilla, Juan M.
trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title_full trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title_fullStr trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title_full_unstemmed trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title_short trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)copper(II)
title_sort trans-di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) n (2),o)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998405/
https://www.ncbi.nlm.nih.gov/pubmed/24764943
http://dx.doi.org/10.1107/S1600536814004334
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