Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate

In the crystal structure of the title compound, 4C(5)H(6)ClN(2) (+)·H(2)P(6)O(18) (4−), the [H(2)P(6)O(18)](4−) anions are interconnected by O—H⋯O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N...

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Detalles Bibliográficos
Autores principales: Hamdi, Ahmed, Khederi, Lamia, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998406/
https://www.ncbi.nlm.nih.gov/pubmed/24765034
http://dx.doi.org/10.1107/S1600536814003584
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author Hamdi, Ahmed
Khederi, Lamia
Rzaigui, Mohamed
author_facet Hamdi, Ahmed
Khederi, Lamia
Rzaigui, Mohamed
author_sort Hamdi, Ahmed
collection PubMed
description In the crystal structure of the title compound, 4C(5)H(6)ClN(2) (+)·H(2)P(6)O(18) (4−), the [H(2)P(6)O(18)](4−) anions are interconnected by O—H⋯O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N—H⋯O and C—H⋯O hydrogen bonds, into a three-dimensional network. The six P atoms of the [H(2)P(6)O(18)](4−) anion form a chair conformation. The complete cyclohexaphosphate anion is generated by inversion symmetry.
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spelling pubmed-39984062014-04-24 Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate Hamdi, Ahmed Khederi, Lamia Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, 4C(5)H(6)ClN(2) (+)·H(2)P(6)O(18) (4−), the [H(2)P(6)O(18)](4−) anions are interconnected by O—H⋯O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N—H⋯O and C—H⋯O hydrogen bonds, into a three-dimensional network. The six P atoms of the [H(2)P(6)O(18)](4−) anion form a chair conformation. The complete cyclohexaphosphate anion is generated by inversion symmetry. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998406/ /pubmed/24765034 http://dx.doi.org/10.1107/S1600536814003584 Text en © Hamdi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hamdi, Ahmed
Khederi, Lamia
Rzaigui, Mohamed
Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title_full Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title_fullStr Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title_full_unstemmed Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title_short Tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
title_sort tetra­kis(2-amino-5-chloro­pyridinium) di­hydrogen cyclo­hexa­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998406/
https://www.ncbi.nlm.nih.gov/pubmed/24765034
http://dx.doi.org/10.1107/S1600536814003584
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AT rzaiguimohamed tetrakis2amino5chloropyridiniumdihydrogencyclohexaphosphate

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