4-Thio­carbamoylpyridin-1-ium iodide

The title salt, C(6)H(7)N(2)S(+)·I(−), crystallizes with two independent cations and two anions in the asymmetric unit. In one of the cations, the dihedral angle between the pyridinium ring and the thioamide group is 28.9 (2)°; in the other it is 33.5 (2)°. In the crystal, N—H⋯S and C—H⋯S hydrogen b...

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Detalles Bibliográficos
Autores principales: Shotonwa, Ibukun O., Boeré, René T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998408/
https://www.ncbi.nlm.nih.gov/pubmed/24765033
http://dx.doi.org/10.1107/S1600536814003511
Descripción
Sumario:The title salt, C(6)H(7)N(2)S(+)·I(−), crystallizes with two independent cations and two anions in the asymmetric unit. In one of the cations, the dihedral angle between the pyridinium ring and the thioamide group is 28.9 (2)°; in the other it is 33.5 (2)°. In the crystal, N—H⋯S and C—H⋯S hydrogen bonds link the independent cations into pairs. These pairs form a three-dimensional network through additional N—H⋯I and C—H⋯I hydrogen bonds to the anions.

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