2-(4,5-Dimeth­oxy-2-nitro­phen­yl)-4-meth­oxy-3-methyl-9-phenyl­sulfonyl-9H-carbazole

In the title compound, C(28)H(24)N(2)O(7)S, the carbazole system is essentially planar, with a maximum deviation of 0.0644 (19) Å for the C atom connected to the 4,5-dimeth­oxy-2-nitro­phenyl group. The dihedral angle between the carbazole moiety and the dimethoxy-substituted nitrophenyl ring is 58....

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Detalles Bibliográficos
Autores principales: Narayanan, P., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998409/
https://www.ncbi.nlm.nih.gov/pubmed/24765031
http://dx.doi.org/10.1107/S1600536814003535
Descripción
Sumario:In the title compound, C(28)H(24)N(2)O(7)S, the carbazole system is essentially planar, with a maximum deviation of 0.0644 (19) Å for the C atom connected to the 4,5-dimeth­oxy-2-nitro­phenyl group. The dihedral angle between the carbazole moiety and the dimethoxy-substituted nitrophenyl ring is 58.55 (7)°. The sulfonyl group forms two intra­molecular C—H⋯O bonds with the adjacent carbazole system, forming two cyclic S(6) motifs. In the crystal, mol­ecules are linked along the a axis in bands consisting of cyclic R (3) (3)(15) motifs through two further C—H⋯O hydrogen bonds.

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