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Fluoren-9-one oxime

In the title mol­ecule, C(13)H(9)NO, the fluorene system and the oxime group non-H atoms are essentially coplanar, with a maximum deviation from the fluorene mean plane of 0.079 (2) Å for the oxime O atom. A short intra­molecular C—H⋯O generates an S(6) ring. In the crystal, mol­ecules related by a...

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Autores principales: Bugenhagen, Bernhard, Al Jasem, Yosef, Al-Azani, Mariam, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998413/
https://www.ncbi.nlm.nih.gov/pubmed/24764980
http://dx.doi.org/10.1107/S1600536814002669
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author Bugenhagen, Bernhard
Al Jasem, Yosef
Al-Azani, Mariam
Thiemann, Thies
author_facet Bugenhagen, Bernhard
Al Jasem, Yosef
Al-Azani, Mariam
Thiemann, Thies
author_sort Bugenhagen, Bernhard
collection PubMed
description In the title mol­ecule, C(13)H(9)NO, the fluorene system and the oxime group non-H atoms are essentially coplanar, with a maximum deviation from the fluorene mean plane of 0.079 (2) Å for the oxime O atom. A short intra­molecular C—H⋯O generates an S(6) ring. In the crystal, mol­ecules related by a twofold screw axis are connected by O—H⋯N hydrogen bonds, forming [100] chains Within these chains, mol­ecules related by a unit translation along [100] show π–π stacking inter­actions between their fluorene ring systems with an inter­planar distance of 3.347 (2) Å. The dihedral angle between the fluorene units of adjacent mol­ecules along the helix is 88.40 (2)°. There is a short C—H⋯π contact between the fluorene groups belonging to neighbouring chains.
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spelling pubmed-39984132014-04-24 Fluoren-9-one oxime Bugenhagen, Bernhard Al Jasem, Yosef Al-Azani, Mariam Thiemann, Thies Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(13)H(9)NO, the fluorene system and the oxime group non-H atoms are essentially coplanar, with a maximum deviation from the fluorene mean plane of 0.079 (2) Å for the oxime O atom. A short intra­molecular C—H⋯O generates an S(6) ring. In the crystal, mol­ecules related by a twofold screw axis are connected by O—H⋯N hydrogen bonds, forming [100] chains Within these chains, mol­ecules related by a unit translation along [100] show π–π stacking inter­actions between their fluorene ring systems with an inter­planar distance of 3.347 (2) Å. The dihedral angle between the fluorene units of adjacent mol­ecules along the helix is 88.40 (2)°. There is a short C—H⋯π contact between the fluorene groups belonging to neighbouring chains. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998413/ /pubmed/24764980 http://dx.doi.org/10.1107/S1600536814002669 Text en © Bugenhagen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bugenhagen, Bernhard
Al Jasem, Yosef
Al-Azani, Mariam
Thiemann, Thies
Fluoren-9-one oxime
title Fluoren-9-one oxime
title_full Fluoren-9-one oxime
title_fullStr Fluoren-9-one oxime
title_full_unstemmed Fluoren-9-one oxime
title_short Fluoren-9-one oxime
title_sort fluoren-9-one oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998413/
https://www.ncbi.nlm.nih.gov/pubmed/24764980
http://dx.doi.org/10.1107/S1600536814002669
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