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(3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenylethyl]-3,4-dihydroisoquinolin-2-ium tetrafluoridoborate
The title salt, C(24)H(24)N(+)·BF(4) (−), is one of two possible diastereoisomers having a different configuration of the asymmetric centre in the α-phenylethyl substituent, whose absolute configuration was established to be R. The two phenyl substituents of the cation have a cofacial orientation,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998414/ https://www.ncbi.nlm.nih.gov/pubmed/24764972 http://dx.doi.org/10.1107/S160053681400230X |
Sumario: | The title salt, C(24)H(24)N(+)·BF(4) (−), is one of two possible diastereoisomers having a different configuration of the asymmetric centre in the α-phenylethyl substituent, whose absolute configuration was established to be R. The two phenyl substituents of the cation have a cofacial orientation, albeit with a long centroid–centroid separation of 4.129 (3) Å. The crystal structure exhibits numerous C—H⋯F contacts between counter-ions, with the tetrafluoridoborate anion surrounded by five iminium cations. |
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