(3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate

The title salt, C(24)H(24)N(+)·BF(4) (−), is one of two possible dias­tereoisomers having a different configuration of the asymmetric centre in the α-phenyl­ethyl substituent, whose absolute configuration was established to be R. The two phenyl substituents of the cation have a cofacial orientation,...

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Detalles Bibliográficos
Autores principales: Ben Ali, Karim, Retailleau, Pascal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998414/
https://www.ncbi.nlm.nih.gov/pubmed/24764972
http://dx.doi.org/10.1107/S160053681400230X
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author Ben Ali, Karim
Retailleau, Pascal
author_facet Ben Ali, Karim
Retailleau, Pascal
author_sort Ben Ali, Karim
collection PubMed
description The title salt, C(24)H(24)N(+)·BF(4) (−), is one of two possible dias­tereoisomers having a different configuration of the asymmetric centre in the α-phenyl­ethyl substituent, whose absolute configuration was established to be R. The two phenyl substituents of the cation have a cofacial orientation, albeit with a long centroid–centroid separation of 4.129 (3) Å. The crystal structure exhibits numerous C—H⋯F contacts between counter-ions, with the tetra­fluorido­borate anion surrounded by five iminium cations.
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spelling pubmed-39984142014-04-24 (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate Ben Ali, Karim Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(24)H(24)N(+)·BF(4) (−), is one of two possible dias­tereoisomers having a different configuration of the asymmetric centre in the α-phenyl­ethyl substituent, whose absolute configuration was established to be R. The two phenyl substituents of the cation have a cofacial orientation, albeit with a long centroid–centroid separation of 4.129 (3) Å. The crystal structure exhibits numerous C—H⋯F contacts between counter-ions, with the tetra­fluorido­borate anion surrounded by five iminium cations. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998414/ /pubmed/24764972 http://dx.doi.org/10.1107/S160053681400230X Text en © Ben Ali and Retailleau 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ben Ali, Karim
Retailleau, Pascal
(3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title_full (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title_fullStr (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title_full_unstemmed (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title_short (3R,4S)-3-Methyl-4-phenyl-2-[(R)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
title_sort (3r,4s)-3-methyl-4-phenyl-2-[(r)-1-phenyl­eth­yl]-3,4-di­hydro­isoquinolin-2-ium tetra­fluorido­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998414/
https://www.ncbi.nlm.nih.gov/pubmed/24764972
http://dx.doi.org/10.1107/S160053681400230X
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