Bis(2,6-di­methyl­anilinium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II)

In the title compound, (C(8)H(12)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], the Co(2+) ion lies on a crystallographic inversion centre and adopts a slightly distorted octa­hedral CoO(6) coordination geometry arising from two chelating diphosphate [H(2)P(2)O(7)](2−) ligands and two trans water mol­ecules....

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Detalles Bibliográficos
Autores principales: Saad, Ahlem Ben, Selmi, Ahmed, Rzaigui, Mohamed, Akriche, Samah Toumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998415/
https://www.ncbi.nlm.nih.gov/pubmed/24764950
http://dx.doi.org/10.1107/S1600536814002530
Descripción
Sumario:In the title compound, (C(8)H(12)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], the Co(2+) ion lies on a crystallographic inversion centre and adopts a slightly distorted octa­hedral CoO(6) coordination geometry arising from two chelating diphosphate [H(2)P(2)O(7)](2−) ligands and two trans water mol­ecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] inter­actions. (001) layers of alternating organic cations and complex inorganic anions are apparent.

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