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Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2) O,O′)cobaltate(II)
In the title compound, (C(8)H(12)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], the Co(2+) ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO(6) coordination geometry arising from two chelating diphosphate [H(2)P(2)O(7)](2−) ligands and two trans water molecules....
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998415/ https://www.ncbi.nlm.nih.gov/pubmed/24764950 http://dx.doi.org/10.1107/S1600536814002530 |
| _version_ | 1782313356348096512 |
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| author | Saad, Ahlem Ben Selmi, Ahmed Rzaigui, Mohamed Akriche, Samah Toumi |
| author_facet | Saad, Ahlem Ben Selmi, Ahmed Rzaigui, Mohamed Akriche, Samah Toumi |
| author_sort | Saad, Ahlem Ben |
| collection | PubMed |
| description | In the title compound, (C(8)H(12)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], the Co(2+) ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO(6) coordination geometry arising from two chelating diphosphate [H(2)P(2)O(7)](2−) ligands and two trans water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent. |
| format | Online Article Text |
| id | pubmed-3998415 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39984152014-04-24 Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2) O,O′)cobaltate(II) Saad, Ahlem Ben Selmi, Ahmed Rzaigui, Mohamed Akriche, Samah Toumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(12)N)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)], the Co(2+) ion lies on a crystallographic inversion centre and adopts a slightly distorted octahedral CoO(6) coordination geometry arising from two chelating diphosphate [H(2)P(2)O(7)](2−) ligands and two trans water molecules. In the crystal, the components are linked by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds and weak aromatic π–π stacking [shortest centroid–centroid separation = 3.778 (2) Å] interactions. (001) layers of alternating organic cations and complex inorganic anions are apparent. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998415/ /pubmed/24764950 http://dx.doi.org/10.1107/S1600536814002530 Text en © Saad et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Saad, Ahlem Ben Selmi, Ahmed Rzaigui, Mohamed Akriche, Samah Toumi Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2) O,O′)cobaltate(II) |
| title | Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
O,O′)cobaltate(II) |
| title_full | Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
O,O′)cobaltate(II) |
| title_fullStr | Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
O,O′)cobaltate(II) |
| title_full_unstemmed | Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
O,O′)cobaltate(II) |
| title_short | Bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
O,O′)cobaltate(II) |
| title_sort | bis(2,6-dimethylanilinium) diaquabis(dihydrogen diphosphato-κ(2)
o,o′)cobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998415/ https://www.ncbi.nlm.nih.gov/pubmed/24764950 http://dx.doi.org/10.1107/S1600536814002530 |
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