5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole

The title compound, C(20)H(18)N(4), was obtained via the condensation of 4,5-di­methyl­benzene-1,2-di­amine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The mol­ecule exhibits an S(6) C—H⋯N intra­mole...

Descripción completa

Detalles Bibliográficos
Autores principales: Geiger, David K., DeStefano, Matthew R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998417/
https://www.ncbi.nlm.nih.gov/pubmed/24765049
http://dx.doi.org/10.1107/S1600536814003870
Descripción
Sumario:The title compound, C(20)H(18)N(4), was obtained via the condensation of 4,5-di­methyl­benzene-1,2-di­amine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The mol­ecule exhibits an S(6) C—H⋯N intra­molecular hydrogen-bond motif. In the crystal, C—H⋯N hydrogen bonds link pairs of mol­ecules related by a crystallographic inversion center, forming R (2) (2)(20) rings. Additional weak C—H⋯N hydrogen bonds result in C(9) chains parallel to [001].

Ejemplares similares