5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole

The title compound, C(20)H(18)N(4), was obtained via the condensation of 4,5-di­methyl­benzene-1,2-di­amine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The mol­ecule exhibits an S(6) C—H⋯N intra­mole...

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Detalles Bibliográficos
Autores principales: Geiger, David K., DeStefano, Matthew R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998417/
https://www.ncbi.nlm.nih.gov/pubmed/24765049
http://dx.doi.org/10.1107/S1600536814003870
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author Geiger, David K.
DeStefano, Matthew R.
author_facet Geiger, David K.
DeStefano, Matthew R.
author_sort Geiger, David K.
collection PubMed
description The title compound, C(20)H(18)N(4), was obtained via the condensation of 4,5-di­methyl­benzene-1,2-di­amine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The mol­ecule exhibits an S(6) C—H⋯N intra­molecular hydrogen-bond motif. In the crystal, C—H⋯N hydrogen bonds link pairs of mol­ecules related by a crystallographic inversion center, forming R (2) (2)(20) rings. Additional weak C—H⋯N hydrogen bonds result in C(9) chains parallel to [001].
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spelling pubmed-39984172014-04-24 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole Geiger, David K. DeStefano, Matthew R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(18)N(4), was obtained via the condensation of 4,5-di­methyl­benzene-1,2-di­amine with pyridine-2-carbaldehyde. The plane of the 2-(pyridin-2-yl) substitutent is canted by 2.75 (11)° from the plane of the benzimidazole system. The mol­ecule exhibits an S(6) C—H⋯N intra­molecular hydrogen-bond motif. In the crystal, C—H⋯N hydrogen bonds link pairs of mol­ecules related by a crystallographic inversion center, forming R (2) (2)(20) rings. Additional weak C—H⋯N hydrogen bonds result in C(9) chains parallel to [001]. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998417/ /pubmed/24765049 http://dx.doi.org/10.1107/S1600536814003870 Text en © Geiger and DeStefano 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Geiger, David K.
DeStefano, Matthew R.
5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title_full 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title_fullStr 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title_full_unstemmed 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title_short 5,6-Dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1H-benzimidazole
title_sort 5,6-dimethyl-2-(pyridin-2-yl)-1-[(pyri­din-2-yl)meth­yl]-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998417/
https://www.ncbi.nlm.nih.gov/pubmed/24765049
http://dx.doi.org/10.1107/S1600536814003870
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