3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan

In the title compound, C(21)H(21)BrO(3)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean planes of the benzo­furan and 2-bromo­phenyl fragments is 82.47 (5)°. In the crystal, mol­ecules related by inversion are paired into dimers via C—H⋯π and π–π inter­actions...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998423/
https://www.ncbi.nlm.nih.gov/pubmed/24765022
http://dx.doi.org/10.1107/S1600536814003547
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author Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(21)H(21)BrO(3)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean planes of the benzo­furan and 2-bromo­phenyl fragments is 82.47 (5)°. In the crystal, mol­ecules related by inversion are paired into dimers via C—H⋯π and π–π inter­actions, the latter are indicated by the short distance of 3.607 (3) Å between the centroids of the furan rings. Inter­molecular C—H⋯O hydrogen bonds and short Br⋯O [3.280 (1) Å] contacts further consolidate the crystal packing.
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spelling pubmed-39984232014-04-24 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)BrO(3)S, the cyclo­hexyl ring adopts a chair conformation. The dihedral angle between the mean planes of the benzo­furan and 2-bromo­phenyl fragments is 82.47 (5)°. In the crystal, mol­ecules related by inversion are paired into dimers via C—H⋯π and π–π inter­actions, the latter are indicated by the short distance of 3.607 (3) Å between the centroids of the furan rings. Inter­molecular C—H⋯O hydrogen bonds and short Br⋯O [3.280 (1) Å] contacts further consolidate the crystal packing. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998423/ /pubmed/24765022 http://dx.doi.org/10.1107/S1600536814003547 Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Lee, Uk
3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_full 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_fullStr 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_full_unstemmed 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_short 3-(2-Bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
title_sort 3-(2-bromo­phenyl­sulfon­yl)-5-cyclo­hexyl-2-methyl-1-benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998423/
https://www.ncbi.nlm.nih.gov/pubmed/24765022
http://dx.doi.org/10.1107/S1600536814003547
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