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4-[(1-Benzyl-1,2,3-triazol-5-yl)meth­yl]-2H-1,4-benzo­thia­zin-3(4H)-one

The asymmetric unit of the title compound, C(18)H(16)N(4)OS, contains two independent mol­ecules of similar conformation, the most relevant difference being the dihedral angle formed by the benzene rings [57.8 (2) and 52.7 (2)°]. The six-membered heterocycle of the benzo­thia­zine fragment exhibits...

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Detalles Bibliográficos
Autores principales: Sebbar, Nada Kheira, El Fal, Mohammed, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998426/
https://www.ncbi.nlm.nih.gov/pubmed/24765048
http://dx.doi.org/10.1107/S1600536814003900
Descripción
Sumario:The asymmetric unit of the title compound, C(18)H(16)N(4)OS, contains two independent mol­ecules of similar conformation, the most relevant difference being the dihedral angle formed by the benzene rings [57.8 (2) and 52.7 (2)°]. The six-membered heterocycle of the benzo­thia­zine fragment exhibits a screw-boat conformation in both mol­ecules. The plane through the triazole ring is nearly perpendicular to those through the fused and terminal benzene rings [dihedral angles of 74.2 (2) and 83.2 (2)° in one mol­ecule, and 77.8 (2) and 82.9 (2)° in the other]. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds into chains parallel to the a-axis direction. The crystal used was a non-merohedral twin, the refined ratio of twin components being 0.85 (10):15 (10).