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N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide
There are two independent molecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent molecule and 0.50:0.50 in the second) with the methyl H atoms also being...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/ https://www.ncbi.nlm.nih.gov/pubmed/24765005 http://dx.doi.org/10.1107/S1600536814003079 |
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author | de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke |
author_facet | de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke |
author_sort | de Oliveira, Adriano Bof |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent molecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first molecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent molecule and 7.60 (13)° in the second. In the crystal, molecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement. |
format | Online Article Text |
id | pubmed-3998428 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984282014-04-24 N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent molecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first molecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent molecule and 7.60 (13)° in the second. In the crystal, molecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998428/ /pubmed/24765005 http://dx.doi.org/10.1107/S1600536814003079 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title |
N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_full |
N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_fullStr |
N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_full_unstemmed |
N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_short |
N-Methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_sort | n-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/ https://www.ncbi.nlm.nih.gov/pubmed/24765005 http://dx.doi.org/10.1107/S1600536814003079 |
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