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N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide

There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being...

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Autores principales: de Oliveira, Adriano Bof, Feitosa, Bárbara Regina Santos, Näther, Christian, Jess, Inke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/
https://www.ncbi.nlm.nih.gov/pubmed/24765005
http://dx.doi.org/10.1107/S1600536814003079
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author de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_facet de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_sort de Oliveira, Adriano Bof
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first mol­ecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent mol­ecule and 7.60 (13)° in the second. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement.
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spelling pubmed-39984282014-04-24 N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)N(3)S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first mol­ecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent mol­ecule and 7.60 (13)° in the second. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998428/ /pubmed/24765005 http://dx.doi.org/10.1107/S1600536814003079 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_full N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_fullStr N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_short N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_sort n-methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/
https://www.ncbi.nlm.nih.gov/pubmed/24765005
http://dx.doi.org/10.1107/S1600536814003079
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